Preparation of reduced graphene oxide/poly(acrylamide) nanocomposite and its adsorption of Pb(II) and methylene blue

Carboxyl groups at the periphery of reduced graphene oxide (RGO) sheets are converted to amine groups by reaction with N-hydroxysuccinimide and 1,3-diaminopropane, and a free-radical polymerization initiator is anchored to the RGO sheets. Poly(acrylamide) (PAM) polymer brushes on RGO sheets (RGO/PAM...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 29(2013), 34 vom: 27. Aug., Seite 10727-36
1. Verfasser: Yang, Yongfang (VerfasserIn)
Weitere Verfasser: Xie, Yulei, Pang, Lichuan, Li, Mao, Song, Xiaohui, Wen, Jianguo, Zhao, Hanying
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2013
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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245 1 0 |a Preparation of reduced graphene oxide/poly(acrylamide) nanocomposite and its adsorption of Pb(II) and methylene blue 
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520 |a Carboxyl groups at the periphery of reduced graphene oxide (RGO) sheets are converted to amine groups by reaction with N-hydroxysuccinimide and 1,3-diaminopropane, and a free-radical polymerization initiator is anchored to the RGO sheets. Poly(acrylamide) (PAM) polymer brushes on RGO sheets (RGO/PAM) are synthesized by in situ free-radical polymerization. The heavy metals, Pb(II), and the benzenoid compounds, methylene blue, (MB) were selected and adsorbed by RGO/PAM composites, and the adsorption capacity of RGO/PAM for Pb(II) and MB was measured. The experimental data of RGO/PAM isotherms for Pb(II) and MB followed the Langmuir isotherm model. The RGO/PAM displays adsorption capacities as high as 1000 and 1530 mg/g for Pb(II) and MB, respectively, indicating RGO/PAM is a good adsorbent for the adsorption of Pb(II) and MB. The adsorption kinetics of Pb(II) and MB onto RGO/PAM can be well fitted to the pseudo-second-order model. The adsorption processes of Pb(II) and MB onto RGO/PAM are spontaneous at 298, 308, and 318 K 
650 4 |a Journal Article 
700 1 |a Xie, Yulei  |e verfasserin  |4 aut 
700 1 |a Pang, Lichuan  |e verfasserin  |4 aut 
700 1 |a Li, Mao  |e verfasserin  |4 aut 
700 1 |a Song, Xiaohui  |e verfasserin  |4 aut 
700 1 |a Wen, Jianguo  |e verfasserin  |4 aut 
700 1 |a Zhao, Hanying  |e verfasserin  |4 aut 
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