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231224s2013 xx |||||o 00| ||eng c |
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|a 10.1021/la402147f
|2 doi
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|a eng
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| 100 |
1 |
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|a Liu, Xiaxia
|e verfasserin
|4 aut
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| 245 |
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|a Size-tailored synthesis of silver quasi-nanospheres by kinetically controlled seeded growth
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|c 2013
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|a Text
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|a ƒaComputermedien
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|a Date Completed 05.03.2014
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|a Date Revised 20.08.2013
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a This paper describes a simple and convenient procedure to synthesize monodisperse silver (Ag) quasi-nanospheres with size tunable in a range of 19-140 nm through a one-step seeded growth strategy. Acetonitrile was employed as a coordinating ligand of a Ag(I) salt in order to achieve a low concentration of elemental Ag after reduction and thus suppression of new nucleation events. Since the addition of the seeds significantly accelerates the reduction reaction of Ag(I) by ascorbic acid, the reaction kinetics was further delicately balanced by tuning the reaction temperature, which proved to be critical in producing Ag quasi-nanospheres with uniform size and shape. This synthesis is highly scalable, so that it provides a simple yet very robust process for producing Ag quasi-nanospheres for many biological, analytical, and catalytic applications which often demand samples in large quantity and widely tunable particle sizes
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|a Journal Article
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|a Yin, Yadong
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|a Gao, Chuanbo
|e verfasserin
|4 aut
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 29(2013), 33 vom: 20. Aug., Seite 10559-65
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|g volume:29
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