Combined technology for clomazone herbicide wastewater treatment : three-dimensional packed-bed electrochemical oxidation and biological contact degradation
The clomazone herbicide wastewater was treated using a combined technology composed of electrochemical catalytic oxidation and biological contact degradation. A new type of electrochemical reactor was fabricated and a Ti/SnO2 electrode was chosen as the anode in electrochemical-oxidation reactor and...
Publié dans: | Water science and technology : a journal of the International Association on Water Pollution Research. - 1986. - 68(2013), 1 vom: 14., Seite 257-60 |
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Auteur principal: | |
Autres auteurs: | , , |
Format: | Article en ligne |
Langue: | English |
Publié: |
2013
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Accès à la collection: | Water science and technology : a journal of the International Association on Water Pollution Research |
Sujets: | Journal Article Research Support, Non-U.S. Gov't Herbicides Isoxazoles Oxazolidinones Water Pollutants, Chemical clomazone 570RAC03NF |
Résumé: | The clomazone herbicide wastewater was treated using a combined technology composed of electrochemical catalytic oxidation and biological contact degradation. A new type of electrochemical reactor was fabricated and a Ti/SnO2 electrode was chosen as the anode in electrochemical-oxidation reactor and stainless steel as the cathode. Ceramic rings loaded with SnO2 were used as three-dimensional electrodes forming a packed bed. The operation parameters that might influence the degradation of organic contaminants in the clomazone wastewater were optimized. When the cell voltage was set at 30 V and the volume of particle electrodes was designed as two-thirds of the volume of the total reactor bed, the chemical oxygen demand (COD) removal rate could reach 82% after 120 min electrolysis, and the ratio of biochemical oxygen demand (BOD)/COD of wastewater increased from 0.12 to 0.38. After 12 h degradation with biological contact oxidation, the total COD removal rate of the combined technology reached 95%, and effluent COD was below 120 mg/L. The results demonstrated that this electrocatalytic oxidation method can be used as a pretreatment for refractory organic wastewater before biological treatment |
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Description: | Date Completed 17.09.2013 Date Revised 04.07.2013 published: Print Citation Status MEDLINE |
ISSN: | 0273-1223 |
DOI: | 10.2166/wst.2013.162 |