Removal of cadmium from water using by-product Crambe abyssinica Hochst seeds as biosorbent material

The effectiveness of Crambe abyssinica Hochst seeds by-product as a biosorbent for the removal of cadmium ions from wastewater was analyzed. The biomass of crambe was characterized by scanning electron microscopy, infrared spectroscopy and determining the point of zero charge. The optimum adsorption...

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Veröffentlicht in:Water science and technology : a journal of the International Association on Water Pollution Research. - 1986. - 68(2013), 1 vom: 14., Seite 227-33
1. Verfasser: Rubio, Fernanda (VerfasserIn)
Weitere Verfasser: Gonçalves, Affonso Celso, Meneghel, Ana Paula, Tarley, Cesar Ricardo Teixeira, Schwantes, Daniel, Coelho, Gustavo Ferreira
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2013
Zugriff auf das übergeordnete Werk:Water science and technology : a journal of the International Association on Water Pollution Research
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Water Pollutants, Chemical Cadmium 00BH33GNGH
Beschreibung
Zusammenfassung:The effectiveness of Crambe abyssinica Hochst seeds by-product as a biosorbent for the removal of cadmium ions from wastewater was analyzed. The biomass of crambe was characterized by scanning electron microscopy, infrared spectroscopy and determining the point of zero charge. The optimum adsorption conditions obtained were 400 mg of biomass in a solution of pH 6.0 and contact time of 60 min to remove 19.342 mg g(-1) cadmium ions. The isotherms of adsorption were constructed and, according to the mathematical linearization, the best fitting followed the Freundlich and Dubinin-Radushkevich models, describing a multilayer adsorption and chemical interaction, also confirmed by the pseudo-second order model and enthalpy value. In the desorption process, about 79% of cadmium ions that had been adsorbed were recovered. The same conditions applied for studying the isotherms of adsorption and desorption were used for comparative study with activated carbon. It was concluded that the use of crambe by-product as biosorbent for cadmium removal in wastewaters was not only a viable alternative to activated carbon, but also required no previous treatment, so it represents a sustainable material with high applicability and low environmental impact
Beschreibung:Date Completed 17.09.2013
Date Revised 21.11.2013
published: Print
Citation Status MEDLINE
ISSN:0273-1223
DOI:10.2166/wst.2013.233