A dense metal-organic framework for enhanced magnetic refrigeration

A dense metal-organic framework for enhanced magnetic refrigeration

Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 25(2013), 33 vom: 06. Sept., Seite 4653-6
1. Verfasser: Lorusso, Giulia (VerfasserIn)
Weitere Verfasser: Sharples, Joseph W, Palacios, Elias, Roubeau, Olivier, Brechin, Euan K, Sessoli, Roberta, Rossin, Andrea, Tuna, Floriana, McInnes, Eric J L, Collison, David, Evangelisti, Marco
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2013
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article gadolinium formate magnetic refrigeration magnetocaloric effect metal-organic frameworks molecule-based magnets
Beschreibung
Zusammenfassung:Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
The three-dimensional metal-organic framework Gd(HCOO)3 is characterized by a relatively compact crystal lattice of weakly interacting Gd(3+) spin centers interconnected via lightweight formate ligands, overall providing a remarkably large magnetic:non-magnetic elemental weight ratio. The resulting magnetocaloric effect per unit volume is decidedly superior in Gd(HCOO)3 than in the best known magnetic refrigerant materials for liquid-helium temperatures and low-moderate applied fields
Beschreibung:Date Completed 01.05.2014
Date Revised 30.09.2020
published: Print-Electronic
Citation Status PubMed-not-MEDLINE
ISSN:1521-4095
DOI:10.1002/adma.201301997