Surface octahedral distortions and atomic design of perovskite interfaces
Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Publié dans: | Advanced materials (Deerfield Beach, Fla.). - 1998. - 25(2013), 29 vom: 07. Aug., Seite 4043-8 |
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Auteur principal: | |
Autres auteurs: | , , , , , , , |
Format: | Article en ligne |
Langue: | English |
Publié: |
2013
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Accès à la collection: | Advanced materials (Deerfield Beach, Fla.) |
Sujets: | Journal Article Research Support, Non-U.S. Gov't interface engineering manganite molecular-beam epitaxy perovskite surface diffraction Calcium Compounds Macromolecular Substances Oxides plus... |
Résumé: | Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. Atomic engineering of perovskite films and interfaces is significantly improved by in situ optimization of reflection high-energy electron diffraction (RHEED) features resulting from surface BO₆ octahedral rotations seen during molecular-beam epitaxy growth. This approach yields Sr-doped manganite films across the phase diagram with magnetotransport properties that are, for the first time, identical to bulk single crystals. Careful structural analysis of manganite/titanate interfaces shows that cation intermixing and unit cell dilations are eliminated, while BO₆ rotations and Jahn-Teller-type elongations are nearly completely suppressed at the interface |
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Description: | Date Completed 17.10.2013 Date Revised 30.09.2020 published: Print-Electronic Citation Status MEDLINE |
ISSN: | 1521-4095 |
DOI: | 10.1002/adma.201301841 |