Ethene/ethane and propene/propane separation via the olefin and paraffin selective metal-organic framework adsorbents CPO-27 and ZIF-8

Two types of metal-organic frameworks (MOFs) have been synthesized and evaluated in the separation of C2 and C3 olefins and paraffins. Whereas Co2(dhtp) (=Co-CPO-27 = Co-MOF-74) and Mg2(dhtp) show an adsorption selectivity for the olefins ethene and propene over the paraffins ethane and propane, the...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 29(2013), 27 vom: 09. Juli, Seite 8592-600
1. Verfasser: Böhme, Ulrike (VerfasserIn)
Weitere Verfasser: Barth, Benjamin, Paula, Carolin, Kuhnt, Andreas, Schwieger, Wilhelm, Mundstock, Alexander, Caro, Jürgen, Hartmann, Martin
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2013
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Alkenes Ethylenes Organometallic Compounds Zeolites 1318-02-1 Cobalt 3G0H8C9362 Paraffin mehr... 8002-74-2 ethylene 91GW059KN7 propylene AUG1H506LY Ethane L99N5N533T Propane T75W9911L6
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245 1 0 |a Ethene/ethane and propene/propane separation via the olefin and paraffin selective metal-organic framework adsorbents CPO-27 and ZIF-8 
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520 |a Two types of metal-organic frameworks (MOFs) have been synthesized and evaluated in the separation of C2 and C3 olefins and paraffins. Whereas Co2(dhtp) (=Co-CPO-27 = Co-MOF-74) and Mg2(dhtp) show an adsorption selectivity for the olefins ethene and propene over the paraffins ethane and propane, the zeolitic imidazolate framework ZIF-8 behaves in the opposite way and preferentially adsorbs the alkane. Consequently, in breakthrough experiments, the olefins or paraffins, respectively, can be separated 
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650 7 |a AUG1H506LY  |2 NLM 
650 7 |a Ethane  |2 NLM 
650 7 |a L99N5N533T  |2 NLM 
650 7 |a Propane  |2 NLM 
650 7 |a T75W9911L6  |2 NLM 
700 1 |a Barth, Benjamin  |e verfasserin  |4 aut 
700 1 |a Paula, Carolin  |e verfasserin  |4 aut 
700 1 |a Kuhnt, Andreas  |e verfasserin  |4 aut 
700 1 |a Schwieger, Wilhelm  |e verfasserin  |4 aut 
700 1 |a Mundstock, Alexander  |e verfasserin  |4 aut 
700 1 |a Caro, Jürgen  |e verfasserin  |4 aut 
700 1 |a Hartmann, Martin  |e verfasserin  |4 aut 
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