|
|
|
|
| LEADER |
01000caa a22002652c 4500 |
| 001 |
NLM228446791 |
| 003 |
DE-627 |
| 005 |
20250215131938.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
231224s2013 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1021/la401607z
|2 doi
|
| 028 |
5 |
2 |
|a pubmed25n0761.xml
|
| 035 |
|
|
|a (DE-627)NLM228446791
|
| 035 |
|
|
|a (NLM)23777261
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Bitter, Julie L
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Anomalous silica colloid stability and gel layer mediated interactions
|
| 264 |
|
1 |
|c 2013
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Completed 05.02.2014
|
| 500 |
|
|
|a Date Revised 16.07.2013
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a Total internal reflection microscopy (TIRM) is used to measure SiO2 colloid ensembles over a glass microscope slide to simultaneously obtain interactions and stability as a function of pH (4-10) and NaCl concentration (0.1-100 mM). Analysis of SiO2 colloid Brownian height excursions yields kT-scale potential energy vs separation profiles, U(h), and diffusivity vs separation profiles, D(h), and determines whether particles are levitated or irreversibly deposited (i.e., stable). By including an impermeable SiO2 "gel layer" when fitting van der Waals, electrostatic, and steric potentials to measured net potentials, gel layers are estimated to be ~10 nm thick and display an ionic strength collapse. The D(h) results indicate consistent surface separation scales for potential energy profiles and hydrodynamic interactions. Our measurements and model indicate how SiO2 gel layers influence van der Waals (e.g., dielectric properties), electrostatics (e.g., shear plane), and steric (e.g., layer thickness) potentials to understand the anomalous high ionic strength and high pH stability of SiO2 colloids
|
| 650 |
|
4 |
|a Journal Article
|
| 700 |
1 |
|
|a Duncan, Gregg A
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Beltran-Villegas, Daniel J
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Fairbrother, D Howard
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Bevan, Michael A
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1985
|g 29(2013), 28 vom: 16. Juli, Seite 8835-44
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnas
|
| 773 |
1 |
8 |
|g volume:29
|g year:2013
|g number:28
|g day:16
|g month:07
|g pages:8835-44
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1021/la401607z
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_22
|
| 912 |
|
|
|a GBV_ILN_350
|
| 912 |
|
|
|a GBV_ILN_721
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 29
|j 2013
|e 28
|b 16
|c 07
|h 8835-44
|