The interaction between natural organic matter in raw waters and pesticide residues : a three dimensional excitation-emission matrix (3DEEM) fluorescence investigation

This paper examines the interaction between dissolved natural organic matter and pesticide residues, both of which are found in raw water sources, using three dimensional excitation-emission matrix (3DEEM) fluorescence spectroscopy. It was observed that pesticide residue at 0.1 mg L(-1) formed a com...

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Veröffentlicht in:Water science and technology : a journal of the International Association on Water Pollution Research. - 1986. - 67(2013), 11 vom: 01., Seite 2428-36
1. Verfasser: Beale, David J (VerfasserIn)
Weitere Verfasser: Porter, Nichola A, Roddick, Felicity A
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2013
Zugriff auf das übergeordnete Werk:Water science and technology : a journal of the International Association on Water Pollution Research
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Benzopyrans Humic Substances Organophosphorus Compounds Pesticide Residues Tannins Triazines Water Pollutants, Chemical Monocrotophos mehr... 6923-22-4 dicrotophos B541I65WBL Atrazine QJA9M5H4IM Simazine SG0C34SMY3 fulvic acid XII14C5FXV hexazinone Y51727MR1Y
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245 1 4 |a The interaction between natural organic matter in raw waters and pesticide residues  |b a three dimensional excitation-emission matrix (3DEEM) fluorescence investigation 
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500 |a Citation Status MEDLINE 
520 |a This paper examines the interaction between dissolved natural organic matter and pesticide residues, both of which are found in raw water sources, using three dimensional excitation-emission matrix (3DEEM) fluorescence spectroscopy. It was observed that pesticide residue at 0.1 mg L(-1) formed a complex with humic-like fluorophores that are commonly found in raw water samples. Applying 3DEEM fluorescence to investigate the humic fractions, it was found that identification of changes in water sources was possible, and, importantly, the presence of a number of pesticides was able to be determined. In addition, the formation of this complex, and the influence of soluble cations and anions upon it, was shown to impact the efficiency of analytical extraction procedures for pesticides; however, 3DEEM fluorescence could be an approach to account for such losses 
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650 4 |a Research Support, Non-U.S. Gov't 
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650 7 |a Humic Substances  |2 NLM 
650 7 |a Organophosphorus Compounds  |2 NLM 
650 7 |a Pesticide Residues  |2 NLM 
650 7 |a Tannins  |2 NLM 
650 7 |a Triazines  |2 NLM 
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650 7 |a Atrazine  |2 NLM 
650 7 |a QJA9M5H4IM  |2 NLM 
650 7 |a Simazine  |2 NLM 
650 7 |a SG0C34SMY3  |2 NLM 
650 7 |a fulvic acid  |2 NLM 
650 7 |a XII14C5FXV  |2 NLM 
650 7 |a hexazinone  |2 NLM 
650 7 |a Y51727MR1Y  |2 NLM 
700 1 |a Porter, Nichola A  |e verfasserin  |4 aut 
700 1 |a Roddick, Felicity A  |e verfasserin  |4 aut 
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