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231224s2013 xx |||||o 00| ||eng c |
| 024 |
7 |
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|a 10.1021/la4002847
|2 doi
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|a eng
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1 |
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|a Haque, Hafiz Ashraful
|e verfasserin
|4 aut
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| 245 |
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|a High-density liquid-crystalline azobenzene polymer brush attained by surface-initiated ring-opening metathesis polymerization
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|c 2013
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|a Date Completed 03.02.2014
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|a Date Revised 29.08.2013
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a High-density polynorbornene azobenzene liquid-crystalline brushes are synthesized on quartz substrates by surface-initiated ring-opening metathesis polymerization (SI-ROMP) using Grubbs third-generation catalyst. The grafting process is controlled over the thickness of the brush from a solid-supported substrate in a stoichiometric manner. A highly ordered liquid-crystal arrangement was formed for such brushes as revealed by spectroscopic measurements and grazing angle X-ray diffraction analysis. Marked features of this method in the structure and photoalignment behavior are unveiled by comparison with brushes made by surface-initiated atom-transfer radical polymerization (SI-ATRP)
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|a Journal Article
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|a Research Support, Non-U.S. Gov't
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|a Kakehi, Soutarou
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Hara, Mitsuo
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Nagano, Shusaku
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Seki, Takahiro
|e verfasserin
|4 aut
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| 773 |
0 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 29(2013), 25 vom: 25. Juni, Seite 7571-5
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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| 773 |
1 |
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|g volume:29
|g year:2013
|g number:25
|g day:25
|g month:06
|g pages:7571-5
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