New tricks for old molecules : development and application of porous N-doped, carbonaceous membranes for CO2 separation
Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Veröffentlicht in: | Advanced materials (Deerfield Beach, Fla.). - 1998. - 25(2013), 30 vom: 14. Aug., Seite 4152-8 |
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1. Verfasser: | |
Weitere Verfasser: | , , , , , , , , |
Format: | Online-Aufsatz |
Sprache: | English |
Veröffentlicht: |
2013
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Zugriff auf das übergeordnete Werk: | Advanced materials (Deerfield Beach, Fla.) |
Schlagworte: | Journal Article Research Support, Non-U.S. Gov't Research Support, U.S. Gov't, Non-P.H.S. CO2 separation N-doped membrane trimerization of acetyl groups Membranes, Artificial Pyrroles Carbon Dioxide 142M471B3J |
Zusammenfassung: | Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. A new strategy is successfully applied to "old" acetyl compounds. A free-standing, porous, N-doped carbonaceous membrane is facilely prepared from the thermal treatment of a pyrrole-ring-containing polymeric membrane based on the superacid-catalyzed copolymerization of acetyl monomers. An exceptional ideal CO2 /N2 permselectivity of 43.2 is achieved with a good CO2 permeability of 1149.3 Barrer, exceeding the recent upper bound for CO2 /N2 |
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Beschreibung: | Date Completed 17.10.2013 Date Revised 30.09.2020 published: Print-Electronic Citation Status MEDLINE |
ISSN: | 1521-4095 |
DOI: | 10.1002/adma.201300793 |