Formation of MgO-supported manganese carbonyl complexes by chemisorption of Mn(CO)5CH3

MgO-supported manganese carbonyl complexes were prepared by chemical vapor deposition of Mn(CO)5CH3 on partially dehydroxylated, high-area MgO powder. X-ray absorption spectra identify the resultant surface species, on average, as Mn(CO)4(Os)2 (where the two oxygen ligands are part of the MgO surfac...

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Veröffentlicht in:	Langmuir : the ACS journal of surfaces and colloids. - 1992. - 29(2013), 21 vom: 28. Mai, Seite 6279-86
1. Verfasser:	Khabuanchalad, Supattra (VerfasserIn)
Weitere Verfasser:	Wittayakun, Jatuporn, Lobo-Lapidus, Rodrigo J, Stoll, Stefan, Britt, R David, Gates, Bruce C
Format:	Online-Aufsatz
Sprache:	English
Veröffentlicht:	2013
Zugriff auf das übergeordnete Werk:	Langmuir : the ACS journal of surfaces and colloids
Schlagworte:	Journal Article Research Support, Non-U.S. Gov't Research Support, U.S. Gov't, Non-P.H.S. Organometallic Compounds Magnesium Oxide 3A3U0GI71G Manganese 42Z2K6ZL8P Carbon Monoxide 7U1EE4V452