Ordered monomolecular layers as a template for the regular arrangement of gold nanoparticles

Ordered arrays of metal nanoparticles are important for nanoelectronic and nanophotonic applications. Here, we report the formation of self-assembled arrays of gold nanoparticles on molecular layers of diacetylene compounds on a MoS2(0001) substrate. The arrangement of gold nanoparticles is observed...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 29(2013), 24 vom: 18. Juni, Seite 7334-43
1. Verfasser: Makarova, Marina (VerfasserIn)
Weitere Verfasser: Mandal, Swapan K, Okawa, Yuji, Aono, Masakazu
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2013
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Gold 7440-57-5
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520 |a Ordered arrays of metal nanoparticles are important for nanoelectronic and nanophotonic applications. Here, we report the formation of self-assembled arrays of gold nanoparticles on molecular layers of diacetylene compounds on a MoS2(0001) substrate. The arrangement of gold nanoparticles is observed using scanning tunneling microscopy. When gold is deposited on a self-assembled monolayer of 10,12-nonacosadiynoic acid or 10,12-octadecadiynoic acid on a MoS2(0001) substrate, the ordered array of diacetylene moieties in the molecular layer serves as a template for the formation of ordered arrays of gold nanoparticles. In contrast, when gold is deposited on a pristine MoS2(0001) surface or on a molecular layer of stearic acid, the gold nanoparticles are randomly distributed on the surface. It is found that the arrangement of gold nanoparticles is largely determined by the deposition rate; faster deposition results in more ordered arrays of gold nanoparticles. Our observations confirm the role of unsaturated π systems in molecules acting as a template for the regular arrangement of gold nanoparticles; this work will open up new possibilities for interfacial nanoarchitectonics 
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700 1 |a Mandal, Swapan K  |e verfasserin  |4 aut 
700 1 |a Okawa, Yuji  |e verfasserin  |4 aut 
700 1 |a Aono, Masakazu  |e verfasserin  |4 aut 
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