Recovering lead from cathode ray tube funnel glass by mechano-chemical extraction in alkaline solution
This study evaluates the efficiency of lead (Pb) extraction from cathode ray tube (CRT) funnel glass in strongly alkaline solution using mechanical activation in a ball mill as the chemical breakage and defects formed in the inner structures will contribute to the easy dissolution of the activated P...
| Veröffentlicht in: | Waste management & research : the journal of the International Solid Wastes and Public Cleansing Association, ISWA. - 1991. - 31(2013), 7 vom: 01. Juli, Seite 759-63 |
|---|---|
| 1. Verfasser: | |
| Weitere Verfasser: | , , , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2013
|
| Zugriff auf das übergeordnete Werk: | Waste management & research : the journal of the International Solid Wastes and Public Cleansing Association, ISWA |
| Schlagworte: | Journal Article Research Support, Non-U.S. Gov't Cathode ray tube (CRT) funnel glass alkaline leaching electrowinning lead mechano-chemical leaching Lead 2P299V784P |
| Zusammenfassung: | This study evaluates the efficiency of lead (Pb) extraction from cathode ray tube (CRT) funnel glass in strongly alkaline solution using mechanical activation in a ball mill as the chemical breakage and defects formed in the inner structures will contribute to the easy dissolution of the activated Pb glass. The combination of mechanical activation and a chemical leaching process in a single operation (mechano-chemical leaching) is more effective than the mechanical activation and subsequent chemical leaching. More than 97% of Pb in the CRT funnel glass can be extracted with a stirring ball mill leaching process in 5 M sodium hydroxide at 70°C. The diameter of the stainless steel balls as the activation medium is 5 mm; the mass ratio of ball to raw materials is 25:1. Pb powder with a purity of 97% can be obtained by electrowinning from the leaching solution. The Pb-depleted solution can be recycled into the leaching step. After Pb is removed, the solid leaching residues can be used for preparation of foam glass. Thus, a novel hydrometallurgical process for recovering Pb from CRT funnel glass in alkaline solution is proposed |
|---|---|
| Beschreibung: | Date Completed 09.01.2014 Date Revised 21.09.2015 published: Print-Electronic Citation Status MEDLINE |
| ISSN: | 1096-3669 |
| DOI: | 10.1177/0734242X13484188 |