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231224s2013 xx |||||o 00| ||eng c |
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7 |
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|a 10.1021/la400293k
|2 doi
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|a pubmed24n0755.xml
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|a eng
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1 |
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|a Creff, Gaelle
|e verfasserin
|4 aut
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1 |
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|a Self-assembly of bridged silsesquioxanes
|b modulating structural evolution via cooperative covalent and noncovalent interactions
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|c 2013
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
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|a Date Completed 12.12.2013
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|a Date Revised 07.05.2013
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|a published: Print-Electronic
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|a Citation Status MEDLINE
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|a The self-assembly of a bis-urea phenylene-bridged silsesquioxane precursor during sol-gel synthesis has been investigated by in situ infrared spectroscopy, optical microscopy, and light scattering. In particular, the evolution of the system as a function of processing time was correlated with covalent interactions associated with increasing polycondensation and noncovalent interactions such as hydrogen bonding. A comprehensive mechanism based on the hydrolysis of the phenylene-bridged organosilane precursor prior to the crystallization of the corresponding bridged silsesquioxane via H-bonding and subsequent irreversible polycondensation is proposed
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|a Journal Article
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|a Organosilicon Compounds
|2 NLM
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|a Pichon, Benoît P
|e verfasserin
|4 aut
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1 |
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|a Blanc, Christophe
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Maurin, David
|e verfasserin
|4 aut
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1 |
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|a Sauvajol, Jean-Louis
|e verfasserin
|4 aut
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1 |
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|a Carcel, Carole
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Moreau, Joël J E
|e verfasserin
|4 aut
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1 |
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|a Roy, Pascale
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Bartlett, John R
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Man, Michel Wong Chi
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Bantignies, Jean-Louis
|e verfasserin
|4 aut
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| 773 |
0 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 29(2013), 18 vom: 07. Mai, Seite 5581-8
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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| 773 |
1 |
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|g volume:29
|g year:2013
|g number:18
|g day:07
|g month:05
|g pages:5581-8
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|u http://dx.doi.org/10.1021/la400293k
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