Photosystem I on graphene as a highly transparent, photoactive electrode

We report the fabrication of a hybrid light-harvesting electrode consisting of photosystem I (PSI) proteins extracted from spinach and adsorbed as a monolayer onto electrically contacted, large-area graphene. The transparency of graphene supports the choice of an opaque mediator at elevated concentr...

Ausführliche Beschreibung

Bibliographische Detailangaben
Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 29(2013), 13 vom: 02. Apr., Seite 4177-80
1. Verfasser: Gunther, Darlene (VerfasserIn)
Weitere Verfasser: LeBlanc, Gabriel, Prasai, Dhiraj, Zhang, Jamie R, Cliffel, David E, Bolotin, Kirill I, Jennings, G Kane
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2013
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, U.S. Gov't, Non-P.H.S. Photosystem I Protein Complex Graphite 7782-42-5
LEADER 01000naa a22002652 4500
001 NLM225913720
003 DE-627
005 20231224070236.0
007 cr uuu---uuuuu
008 231224s2013 xx |||||o 00| ||eng c
024 7 |a 10.1021/la305020c  |2 doi 
028 5 2 |a pubmed24n0753.xml 
035 |a (DE-627)NLM225913720 
035 |a (NLM)23506192 
040 |a DE-627  |b ger  |c DE-627  |e rakwb 
041 |a eng 
100 1 |a Gunther, Darlene  |e verfasserin  |4 aut 
245 1 0 |a Photosystem I on graphene as a highly transparent, photoactive electrode 
264 1 |c 2013 
336 |a Text  |b txt  |2 rdacontent 
337 |a ƒaComputermedien  |b c  |2 rdamedia 
338 |a ƒa Online-Ressource  |b cr  |2 rdacarrier 
500 |a Date Completed 26.09.2013 
500 |a Date Revised 02.04.2013 
500 |a published: Print-Electronic 
500 |a Citation Status MEDLINE 
520 |a We report the fabrication of a hybrid light-harvesting electrode consisting of photosystem I (PSI) proteins extracted from spinach and adsorbed as a monolayer onto electrically contacted, large-area graphene. The transparency of graphene supports the choice of an opaque mediator at elevated concentrations. For example, we report a photocurrent of 550 nA/cm(2) from a monolayer of PSI on graphene in the presence of 20 mM methylene blue, which yields an opaque blue solution. The PSI-modified graphene electrode has a total thickness of less than 10 nm and demonstrates photoactivity that is an order of magnitude larger than that for unmodified graphene, establishing the feasibility of conjoining these nanomaterials as potential constructs in next-generation photovoltaic devices 
650 4 |a Journal Article 
650 4 |a Research Support, U.S. Gov't, Non-P.H.S. 
650 7 |a Photosystem I Protein Complex  |2 NLM 
650 7 |a Graphite  |2 NLM 
650 7 |a 7782-42-5  |2 NLM 
700 1 |a LeBlanc, Gabriel  |e verfasserin  |4 aut 
700 1 |a Prasai, Dhiraj  |e verfasserin  |4 aut 
700 1 |a Zhang, Jamie R  |e verfasserin  |4 aut 
700 1 |a Cliffel, David E  |e verfasserin  |4 aut 
700 1 |a Bolotin, Kirill I  |e verfasserin  |4 aut 
700 1 |a Jennings, G Kane  |e verfasserin  |4 aut 
773 0 8 |i Enthalten in  |t Langmuir : the ACS journal of surfaces and colloids  |d 1992  |g 29(2013), 13 vom: 02. Apr., Seite 4177-80  |w (DE-627)NLM098181009  |x 1520-5827  |7 nnns 
773 1 8 |g volume:29  |g year:2013  |g number:13  |g day:02  |g month:04  |g pages:4177-80 
856 4 0 |u http://dx.doi.org/10.1021/la305020c  |3 Volltext 
912 |a GBV_USEFLAG_A 
912 |a SYSFLAG_A 
912 |a GBV_NLM 
912 |a GBV_ILN_22 
912 |a GBV_ILN_350 
912 |a GBV_ILN_721 
951 |a AR 
952 |d 29  |j 2013  |e 13  |b 02  |c 04  |h 4177-80