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231224s2013 xx |||||o 00| ||eng c |
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|a 10.1021/la400155d
|2 doi
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|a eng
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|a Li, Yinyong
|e verfasserin
|4 aut
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|a Patterned polymer films via reactive silane infusion-induced wrinkling
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|c 2013
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|a Date Completed 20.09.2013
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|a Date Revised 09.04.2013
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a A method for simultaneously patterning and functionalizing thin poly(2-hydroxyethyl methacrylate) films through a reactive silane infusion based wrinkling is developed. Wrinkled patterns with tunable wavelengths on submicrometer size are easily produced over large area surfaces and can express a wide variety of chemical functional groups on the surface. The characteristic wavelength of wrinkling scales linearly with initial film thickness, in agreement with a gradationally swollen film model. Results from X-ray photoelectron spectroscopy confirm that the wrinkled film is composed of two layers: a gradient cross-linked top layer and a uniform un-cross-linked bottom layer. The surface chemical properties of wrinkles can be easily tuned by infusion of different functional silanes. Hierarchical wrinkled patterns with micro/nano structure can be achieved by combining wrinkling with other simple lithography methods. Wrinkled nanopatterns can be used as a mold to transfer the topology to a variety of other materials using nanoimprint lithography
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|a Journal Article
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|a Peterson, Joseph J
|e verfasserin
|4 aut
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1 |
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|a Jhaveri, Sarav B
|e verfasserin
|4 aut
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1 |
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|a Carter, Kenneth R
|e verfasserin
|4 aut
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773 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 29(2013), 14 vom: 09. Apr., Seite 4632-9
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|x 1520-5827
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|g volume:29
|g year:2013
|g number:14
|g day:09
|g month:04
|g pages:4632-9
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|u http://dx.doi.org/10.1021/la400155d
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