Why fluorination of the polar heads reverses the positive sign of the dipole potential of Langmuir monolayers : a vibrational sum frequency spectroscopic study
Natural nonionic amphiphiles forming monolayers, bilayers, micelles, or biomembranes create a positive dipole potential at the boundary with water. In a series of papers we have reported on Langmuir monolayers with CF3 terminals of the polar heads, which show a negative surface dipole potential ΔV (...
Ausführliche Beschreibung
Bibliographische Detailangaben
Veröffentlicht in: | Langmuir : the ACS journal of surfaces and colloids. - 1992. - 29(2013), 15 vom: 16. Apr., Seite 4726-36
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1. Verfasser: |
Karageorgiev, Peter
(VerfasserIn) |
Weitere Verfasser: |
Petrov, Jordan G,
Motschmann, Hubert,
Moehwald, Helmuth |
Format: | Online-Aufsatz
|
Sprache: | English |
Veröffentlicht: |
2013
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Zugriff auf das übergeordnete Werk: | Langmuir : the ACS journal of surfaces and colloids
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Schlagworte: | Journal Article
Research Support, Non-U.S. Gov't
Hydrocarbons, Fluorinated
Water
059QF0KO0R
Ether
0F5N573A2Y |