Why fluorination of the polar heads reverses the positive sign of the dipole potential of Langmuir monolayers : a vibrational sum frequency spectroscopic study

Natural nonionic amphiphiles forming monolayers, bilayers, micelles, or biomembranes create a positive dipole potential at the boundary with water. In a series of papers we have reported on Langmuir monolayers with CF3 terminals of the polar heads, which show a negative surface dipole potential ΔV (...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 29(2013), 15 vom: 16. Apr., Seite 4726-36
1. Verfasser: Karageorgiev, Peter (VerfasserIn)
Weitere Verfasser: Petrov, Jordan G, Motschmann, Hubert, Moehwald, Helmuth
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2013
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Hydrocarbons, Fluorinated Water 059QF0KO0R Ether 0F5N573A2Y