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231224s2013 xx |||||o 00| ||eng c |
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|a 10.1021/la3046753
|2 doi
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|a eng
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| 100 |
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|a Stark, Michael
|e verfasserin
|4 aut
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|a Coverage dependent disorder-order transition of 2H-tetraphenylporphyrin on Cu(111)
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|c 2013
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|a Date Completed 10.09.2013
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|a Date Revised 26.03.2013
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a In this study, we investigate the peculiar coverage dependent supramolecular arrangement of 2H-tetraphenylporhpyrin (2HTPP) on Cu(111) with scanning tunneling microscopy at room-temperature. At low coverage, "slow" diffusion of individual 2HTPP molecules along the close-packed atomic rows of the substrate is observed, and no supramolecular ordering occurs. However, at higher coverage, the formation of ordered, checkerboard-like domains is found, with two molecules per unit cell at different distances from the surface. This behavior is attributed to a complex interplay of site specific molecule-substrate interaction, mainly the strong interaction between the iminic N atoms and Cu substrate atoms, with intermolecular T-type and π-π interactions
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|a Journal Article
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|a Ditze, Stefanie
|e verfasserin
|4 aut
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|a Drost, Martin
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Buchner, Florian
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Steinrück, Hans-Peter
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Marbach, Hubertus
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1985
|g 29(2013), 12 vom: 26. März, Seite 4104-10
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|x 1520-5827
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|g volume:29
|g year:2013
|g number:12
|g day:26
|g month:03
|g pages:4104-10
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|u http://dx.doi.org/10.1021/la3046753
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