Performance enhancement of ZnO photocatalyst via synergic effect of surface oxygen defect and graphene hybridization

ZnO1-x/graphene hybrid photocatalyst was prepared via a facile in-situ reduction of graphene oxide and ZnO1-x surface defect oxide. The hybrid photocatlayst showed enhanced photocatalytic activity for the photodegradation of methylene blue. The photocorrosion of ZnO1-x was successfully inhibited by...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 29(2013), 9 vom: 05. März, Seite 3097-105
1. Verfasser: Bai, Xiaojuan (VerfasserIn)
Weitere Verfasser: Wang, Li, Zong, Ruilong, Lv, Yanhui, Sun, Yiqing, Zhu, Yongfa
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2013
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Antibodies, Catalytic Graphite 7782-42-5 Oxygen S88TT14065 Zinc Oxide SOI2LOH54Z Methylene Blue T42P99266K
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520 |a ZnO1-x/graphene hybrid photocatalyst was prepared via a facile in-situ reduction of graphene oxide and ZnO1-x surface defect oxide. The hybrid photocatlayst showed enhanced photocatalytic activity for the photodegradation of methylene blue. The photocorrosion of ZnO1-x was successfully inhibited by graphene hybridation. ZnO1-x/graphene hybrid photocatalyst with 1.2 wt % graphene showed the optimized photocatalytic activity. The photocatalytic activity of ZnO1-x/graphene-1.2 wt % under visible and UV light was about 4.6 and 1.2 times that of ZnO1-x sample, respectively. The photocurrent intensity of ZnO1-x under visible and UV light irradiation can be enhanced by 2 and 3.5 times by graphene hybridization. The enhancement of photocatalytic activity and photocurrent intensity in ZnO1-x/graphene was attributed to the synergistic effect between graphene and ZnO1-x for high separation efficiency of photoinduced electron-hole pairs mainly resulting from the promotion of HOMO orbit of graphene and the Oi″ defect level of ZnO1-x in ZnO1-x/graphene 
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650 7 |a Oxygen  |2 NLM 
650 7 |a S88TT14065  |2 NLM 
650 7 |a Zinc Oxide  |2 NLM 
650 7 |a SOI2LOH54Z  |2 NLM 
650 7 |a Methylene Blue  |2 NLM 
650 7 |a T42P99266K  |2 NLM 
700 1 |a Wang, Li  |e verfasserin  |4 aut 
700 1 |a Zong, Ruilong  |e verfasserin  |4 aut 
700 1 |a Lv, Yanhui  |e verfasserin  |4 aut 
700 1 |a Sun, Yiqing  |e verfasserin  |4 aut 
700 1 |a Zhu, Yongfa  |e verfasserin  |4 aut 
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