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231224s2013 xx |||||o 00| ||eng c |
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|a 10.1021/la4001076
|2 doi
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|a pubmed24n0750.xml
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|a DE-627
|b ger
|c DE-627
|e rakwb
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|a eng
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|a Rodriguez-Liviano, Sonia
|e verfasserin
|4 aut
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|a Ionic liquid mediated synthesis and surface modification of multifunctional mesoporous Eu:GdF3 nanoparticles for biomedical applications
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|c 2013
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
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|a Date Completed 04.09.2013
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|a Date Revised 21.11.2013
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|a published: Print-Electronic
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|a Citation Status MEDLINE
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|a A procedure for the synthesis of multifunctional europium(III)-doped gadolinium(III) fluoride (Eu:GdF3) nanoparticles (~85 nm) with quasispherical shape by precipitation at 120 °C from diethylene glycol solutions containing lanthanide chlorides and an ionic liquid (1-Butyl, 2-methylimidazolium tetrafluoroborate) as fluoride source has been developed. These nanoparticles were polycrystalline and crystallized into a hexagonal structure, which is unusual for GdF3. They were also mesoporous (pore size = 3.5 Å), having a rather high BET surface area (75 m(2) g(-1)). The luminescent and magnetic (relaxivity) properties of the Eu:GdF3 nanoparticles have been also evaluated in order to assess their potentiality as "in vitro" optical biolabels and contrast agent for magnetic resonance imaging. Finally, a procedure for their functionalization with aspartic-dextran polymers is also reported. The functionalized Eu:GdF3 nanoparticles presented negligible toxicity for Vero cells, which make them suitable for biotecnological applications
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|a Journal Article
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|a Research Support, Non-U.S. Gov't
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|a Ionic Liquids
|2 NLM
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|a Europium
|2 NLM
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|a 444W947O8O
|2 NLM
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|a Gadolinium
|2 NLM
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|a AU0V1LM3JT
|2 NLM
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1 |
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|a Nuñez, Nuria O
|e verfasserin
|4 aut
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|a Rivera-Fernández, Sara
|e verfasserin
|4 aut
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1 |
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|a de la Fuente, Jesus M
|e verfasserin
|4 aut
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|a Ocaña, Manuel
|e verfasserin
|4 aut
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 29(2013), 10 vom: 12. März, Seite 3411-8
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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|g volume:29
|g year:2013
|g number:10
|g day:12
|g month:03
|g pages:3411-8
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|u http://dx.doi.org/10.1021/la4001076
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