Influence of substrate confinement on the phase-correlation in the capillary breakup of arrays of patterned polymer stripes
We investigated the influence of substrate confinement on the capillary breakup of parallel nonaxisymmetric polymer stripes suspended on top of, or confined between, another immiscible polymer pattern. When the residual layer thickness of the pattern was reasonably large, the PS (or PMMA) stripes co...
| Veröffentlicht in: | Langmuir : the ACS journal of surfaces and colloids. - 1992. - 29(2013), 9 vom: 05. März, Seite 3073-9 |
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| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2013
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| Zugriff auf das übergeordnete Werk: | Langmuir : the ACS journal of surfaces and colloids |
| Schlagworte: | Journal Article |
| Zusammenfassung: | We investigated the influence of substrate confinement on the capillary breakup of parallel nonaxisymmetric polymer stripes suspended on top of, or confined between, another immiscible polymer pattern. When the residual layer thickness of the pattern was reasonably large, the PS (or PMMA) stripes confined within PMMA (or PS) trenches broke up, either nucleated, out-of-phase, or without clear phase correlation depending on the geometry and viscosity ratio between the two polymers. In stark contrast, for the two extreme cases of viscosity ratios we studied, in-phase breakup of confined polymer stripes was always observed when the alternating PS/PMMA stripes were formed, that is, without residual layer, regardless of the specific geometry |
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| Beschreibung: | Date Completed 16.08.2013 Date Revised 06.03.2013 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1520-5827 |
| DOI: | 10.1021/la304528t |