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231224s2013 xx |||||o 00| ||eng c |
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7 |
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|a 10.1021/la304147j
|2 doi
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|a pubmed24n0749.xml
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|a DE-627
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|a eng
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|a Saha, Debraj
|e verfasserin
|4 aut
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|a Anchoring of palladium onto surface of porous metal-organic framework through post-synthesis modification and studies on Suzuki and Stille coupling reactions under heterogeneous condition
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|c 2013
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
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|2 rdacarrier
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|a Date Completed 16.08.2013
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|a Date Revised 06.03.2013
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a An ecofriendly solid catalyst has been synthesized by anchoring palladium(II) into post synthetically modified metal organic framework IRMOF-3. The pore of IRMOF-3 was first modified with pyridine-2-aldehyde. The amine group of IRMOF-3 upon condensation with pyridine-2-aldehyde afforded a bidentate Schiff base moiety in the porous matrix. The Schiff base moieties were used to anchor palladium(II) ions. The prepared catalyst has been characterized by UV-vis, IR spectroscopy, X-ray powder diffraction, and nitrogen sorption measurements. Framework structure of the catalyst is not being destroyed in the multistep synthesis procedure as evidenced in X-ray powder diffraction studies. The catalyst has shown high activity toward the Suzuki and Stille cross-coupling reaction in 20% H2O/EtOH and EtOH medium, respectively, at 80 °C. The immobilized complex did not leach or decompose during the catalytic reactions, showing practical advantages over the homogeneous catalysis
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|a Journal Article
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|a Sen, Rupam
|e verfasserin
|4 aut
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1 |
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|a Maity, Tanmoy
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Koner, Subratanath
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 29(2013), 9 vom: 05. März, Seite 3140-51
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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| 773 |
1 |
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|g volume:29
|g year:2013
|g number:9
|g day:05
|g month:03
|g pages:3140-51
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|u http://dx.doi.org/10.1021/la304147j
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