Nanocomposites derived from montmorillonite and metallosupramolecular polyelectrolytes : modular compounds for electrorheological fluids

Nanocomposites made from Na-montmorillonite and metallo-supramolecular polyelectrolytes (MEPE) based on nickel and ditopic bis-terpyridine ligands are prepared by an aqueous synthesis. Intercalation is confirmed by IR-spectroscopy, thermogravimetric analysis, and X-ray powder diffraction. The rheolo...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 29(2013), 6 vom: 12. Feb., Seite 1743-7
1. Verfasser: Geist, Matthias F (VerfasserIn)
Weitere Verfasser: Boussois, Kevin, Smith, Agnes, Peyratout, Claire S, Kurth, Dirk G
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2013
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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520 |a Nanocomposites made from Na-montmorillonite and metallo-supramolecular polyelectrolytes (MEPE) based on nickel and ditopic bis-terpyridine ligands are prepared by an aqueous synthesis. Intercalation is confirmed by IR-spectroscopy, thermogravimetric analysis, and X-ray powder diffraction. The rheological response in the presence of an electric field of the dispersed nanocomposites in silicone oil is measured with a rheometer. The nanocomposites show a distinct electrorheological effect depending on the concentration and the kind of intercalated species. The effect occurs with a low content of active material while only very small currents are observed 
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700 1 |a Smith, Agnes  |e verfasserin  |4 aut 
700 1 |a Peyratout, Claire S  |e verfasserin  |4 aut 
700 1 |a Kurth, Dirk G  |e verfasserin  |4 aut 
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