Chemical treatment of chelated metal finishing wastes

This study evaluated two chemical approaches for treatment of commingled cadmium-cyanide (Cd-CN) and zinc-nickel (Zn-Ni) wastewaters. The first approach, which involved application of sodium hypochlorite (NaOCl), focused on elimination of chelating substances. The second approach evaluated the use o...

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Veröffentlicht in:Water environment research : a research publication of the Water Environment Federation. - 1998. - 84(2012), 12 vom: 10. Dez., Seite 2086-9
1. Verfasser: McFarland, Michael J (VerfasserIn)
Weitere Verfasser: Glarborg, Christen, Ross, Mark A
Format: Aufsatz
Sprache:English
Veröffentlicht: 2012
Zugriff auf das übergeordnete Werk:Water environment research : a research publication of the Water Environment Federation
Schlagworte:Journal Article Chelating Agents Cyanides Dimethyldithiocarbamate Industrial Waste Metals, Heavy Waste Water Cadmium 00BH33GNGH Nickel mehr... 7OV03QG267 Sodium Hypochlorite DY38VHM5OD Zinc J41CSQ7QDS
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245 1 0 |a Chemical treatment of chelated metal finishing wastes 
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500 |a Date Completed 19.04.2013 
500 |a Date Revised 07.12.2022 
500 |a published: Print 
500 |a Citation Status MEDLINE 
520 |a This study evaluated two chemical approaches for treatment of commingled cadmium-cyanide (Cd-CN) and zinc-nickel (Zn-Ni) wastewaters. The first approach, which involved application of sodium hypochlorite (NaOCl), focused on elimination of chelating substances. The second approach evaluated the use of sodium dimethyldithiocarbamate (DMDTC) to specifically target and precipitate regulated heavy metals. Results demonstrated that by maintaining a pH of 10.0 and an oxidation-reduction potential (ORP) value of +600 mV, NaOCl treatment was effective in eliminating all chelating substances. Cadmium, chromium, nickel, and zinc solution concentrations were reduced from 0.27, 4.44, 0.06, and 0.10 ppm to 0.16, 0.17, 0.03, and 0.06 ppm, respectively. Similarly, a 1% DMDTC solution reduced these same metal concentrations in commingled wastewater to 0.009, 1.142, 0.036, and 0.320 ppm. Increasing the DMDTC concentration to 2% improved the removal of all regulated heavy metals except zinc, the removal of which at high pH values is limited by its amphotericity 
650 4 |a Journal Article 
650 7 |a Chelating Agents  |2 NLM 
650 7 |a Cyanides  |2 NLM 
650 7 |a Dimethyldithiocarbamate  |2 NLM 
650 7 |a Industrial Waste  |2 NLM 
650 7 |a Metals, Heavy  |2 NLM 
650 7 |a Waste Water  |2 NLM 
650 7 |a Cadmium  |2 NLM 
650 7 |a 00BH33GNGH  |2 NLM 
650 7 |a Nickel  |2 NLM 
650 7 |a 7OV03QG267  |2 NLM 
650 7 |a Sodium Hypochlorite  |2 NLM 
650 7 |a DY38VHM5OD  |2 NLM 
650 7 |a Zinc  |2 NLM 
650 7 |a J41CSQ7QDS  |2 NLM 
700 1 |a Glarborg, Christen  |e verfasserin  |4 aut 
700 1 |a Ross, Mark A  |e verfasserin  |4 aut 
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