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231224s2013 xx |||||o 00| ||eng c |
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|a 10.1021/la304874y
|2 doi
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|a pubmed24n0747.xml
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|a eng
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| 100 |
1 |
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|a Yu, Yixuan
|e verfasserin
|4 aut
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| 245 |
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|a Room temperature hydrosilylation of silicon nanocrystals with bifunctional terminal alkenes
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|c 2013
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|a Text
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|a ƒaComputermedien
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|a Date Completed 29.07.2013
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|a Date Revised 07.06.2023
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|a published: Print-Electronic
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|a Citation Status MEDLINE
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|a H-terminated Si nanocrystals undergo room temperature hydrosilylation with bifunctional alkenes with distal polar moieties-ethyl ester, methyl ester, or carboxylic acids-without the aid of light or added catalyst. The passivated Si nanocrystals exhibit bright photoluminescence (PL) and disperse in polar solvents, including water. We propose a reaction mechanism in which ester or carboxylic acid groups facilitate direct nucleophilic attack of the highly curved Si surface of the nanocrystals by the alkene
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|a Journal Article
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|a Research Support, N.I.H., Extramural
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|a Research Support, Non-U.S. Gov't
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|a Alkenes
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|a Carboxylic Acids
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|a Esters
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|a Silicon
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|a Z4152N8IUI
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|a Hessel, Colin M
|e verfasserin
|4 aut
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1 |
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|a Bogart, Timothy D
|e verfasserin
|4 aut
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|a Panthani, Matthew G
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|4 aut
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|a Rasch, Michael R
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|a Korgel, Brian A
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 29(2013), 5 vom: 05. Feb., Seite 1533-40
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|x 1520-5827
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|g volume:29
|g year:2013
|g number:5
|g day:05
|g month:02
|g pages:1533-40
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