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231224s2013 xx |||||o 00| ||eng c |
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|a 10.1021/la304453h
|2 doi
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|a pubmed24n0746.xml
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|a DE-627
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|a eng
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1 |
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|a Stöter, Matthias
|e verfasserin
|4 aut
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|a Nanoplatelets of sodium hectorite showing aspect ratios of ≈20,000 and superior purity
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|c 2013
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
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|2 rdacarrier
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|a Date Completed 08.07.2013
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|a Date Revised 29.01.2013
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a Applying a combination of melt synthesis followed by long-term annealing a fluorohectorite is obtained which is unique with respect to homogeneity, purity, and particle size. Counterintuitively, the hectorite undergoes a disorder-to-order transition upon swelling to the level of the bilayer hydrate. Alkylammonium-exchanged samples show at any chain length only a single basal spacing corroborating a nicely homogeneous layer charge density. Its intracrystalline reactivity improves greatly upon annealing, making it capable to spontaneously and completely disintegrate into single clay lamellae of 1 nm thickness. Realizing exceptional aspect ratios of around 20,000 upon delamination, this synthetic clay will offer unprecedented potential as functional filler in highly transparent nanocomposites with superior gas barrier and mechanical properties
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|a Journal Article
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|a Kunz, Daniel A
|e verfasserin
|4 aut
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|a Schmidt, Marko
|e verfasserin
|4 aut
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|a Hirsemann, Dunja
|e verfasserin
|4 aut
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|a Kalo, Hussein
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Putz, Bernd
|e verfasserin
|4 aut
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| 700 |
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|a Senker, Jürgen
|e verfasserin
|4 aut
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|a Breu, Josef
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 29(2013), 4 vom: 29. Jan., Seite 1280-5
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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| 773 |
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|g volume:29
|g year:2013
|g number:4
|g day:29
|g month:01
|g pages:1280-5
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|u http://dx.doi.org/10.1021/la304453h
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