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231224s2013 xx |||||o 00| ||eng c |
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|a 10.1021/la3045576
|2 doi
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|a pubmed24n0745.xml
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|a (DE-627)NLM223600369
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|a (NLM)23256867
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|a DE-627
|b ger
|c DE-627
|e rakwb
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|a eng
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|a Higuchi, Rintaro
|e verfasserin
|4 aut
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|a Construction and characterization of molecular nonwoven fabrics consisting of cross-linked poly(γ-methyl-L-glutamate)
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|c 2013
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
|b cr
|2 rdacarrier
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|a Date Completed 06.01.2014
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|a Date Revised 18.06.2013
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|a published: Print-Electronic
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|a Citation Status MEDLINE
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|a Molecular nonwoven fabrics in the form of ultrathin layer-by-layer (LbL) helical polymer films with covalent cross-linking were assembled on substrates by an alternate ester-amide exchange reaction between poly(γ-methyl L-glutamate) (PMLG) and cross-linking agent ethylene diamine or 4,4'-diamino azobenzene. The regular growth of helical monolayers without excessive adsorption and the formation of amide bonds were confirmed by ultraviolet-visible (UV-vis) spectrophotometry, quartz crystal microbalance (QCM), ellipsometry, and infrared reflection-absorption spectroscopy (IR-RAS) measurements. Nanostructures with high uniformity and ultrathin films with few defects formed by helical rod segments of PMLG were characterized by atomic force microscopy (AFM) and Kelvin probe force microscopy (KFM)
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|a Journal Article
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|a Research Support, Non-U.S. Gov't
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|a Cross-Linking Reagents
|2 NLM
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|a poly-gamma-methylglutamate
|2 NLM
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|a 25086-16-2
|2 NLM
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|a Polyglutamic Acid
|2 NLM
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|a 25513-46-6
|2 NLM
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|a Hirano, Megumi
|e verfasserin
|4 aut
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|a Ashaduzzaman, Md
|e verfasserin
|4 aut
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|a Yilmaz, Neval
|e verfasserin
|4 aut
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|a Sumino, Tatsunori
|e verfasserin
|4 aut
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|a Kodama, Daisuke
|e verfasserin
|4 aut
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|a Chiba, Sayuri
|e verfasserin
|4 aut
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|a Uemura, Shinobu
|e verfasserin
|4 aut
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|a Nishiyama, Katsuhiko
|e verfasserin
|4 aut
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| 700 |
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|a Ohira, Akihiro
|e verfasserin
|4 aut
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|a Fujiki, Michiya
|e verfasserin
|4 aut
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|a Kunitake, Masashi
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 29(2013), 24 vom: 18. Juni, Seite 7478-87
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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| 773 |
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|g volume:29
|g year:2013
|g number:24
|g day:18
|g month:06
|g pages:7478-87
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|u http://dx.doi.org/10.1021/la3045576
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