Preparation and adsorption performance of MnO2/PAC composite towards aqueous glyphosate

Glyphosate (N-phosphonomethylglycine (PMG)) is the organophosphate herbicide most widely used in the world, and industrial production of PMG generates large quantities of wastewater. A manganese dioxide-coated powdered activated carbon (MnO2/PAC) composite was synthesized and investigated for the ad...

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Veröffentlicht in:Environmental technology. - 1993. - 33(2012), 16-18 vom: 14. Sept., Seite 2049-56
1. Verfasser: Cui, Hao (VerfasserIn)
Weitere Verfasser: Li, Qin, Qian, Yan, Zhang, Qiu, Zhai, Jianping
Format: Aufsatz
Sprache:English
Veröffentlicht: 2012
Zugriff auf das übergeordnete Werk:Environmental technology
Schlagworte:Evaluation Study Journal Article Research Support, Non-U.S. Gov't Anions Manganese Compounds Oxides Water Pollutants, Chemical Charcoal 16291-96-6 manganese oxide mehr... 64J2OA7MH3 Glycine TE7660XO1C
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520 |a Glyphosate (N-phosphonomethylglycine (PMG)) is the organophosphate herbicide most widely used in the world, and industrial production of PMG generates large quantities of wastewater. A manganese dioxide-coated powdered activated carbon (MnO2/PAC) composite was synthesized and investigated for the adsorption of PMG from wastewater. The results of scanning electron microscopy (SEM) combined with energy-dispersive X-ray spectrometry (EDAX) revealed that MnO2 was formed on the surface of the carbon during the modification process. Batch adsorption results showed that the optimal pH for glyphosate adsorption on MnO2/PAC was 3.0. In the range 0.01(-1) molL(-1), glyphosate removal by MnO2/PAC decreased with an increase in ionic strength. Among the coexistent anions, only phosphate showed significant inhibition of PMG removal due to competitive complexation. Batch studies revealed that MnO2/PAC could reach a maximum PMG adsorption capacity of 283 mg g(-1). The Langmuir equilibrium model was found to be suitable for describing PMG sorption, and kinetic studies revealed that adsorption followed second-order rate kinetics. It was also proved that the adsorbed PMG could be effectively desorbed from MnO2/PAC in 1.0 molL(-1) NaOH. All of these results implied that the MnO2/PAC composite may be used as an effective adsorbent for recycling PMG from wastewater 
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650 4 |a Research Support, Non-U.S. Gov't 
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650 7 |a Oxides  |2 NLM 
650 7 |a Water Pollutants, Chemical  |2 NLM 
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650 7 |a 16291-96-6  |2 NLM 
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700 1 |a Li, Qin  |e verfasserin  |4 aut 
700 1 |a Qian, Yan  |e verfasserin  |4 aut 
700 1 |a Zhang, Qiu  |e verfasserin  |4 aut 
700 1 |a Zhai, Jianping  |e verfasserin  |4 aut 
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