Emission wavelength tuning in rare earth fluoride upconverting nanoparticles decorated with dye-coated titanate nanotubes

The radiative energy transfer from rare earth fluoride upconverting (UC) Na(x)Li(y)YF(4):Yb(3+),Er(3+) nanoparticles to rhodamine dyes has been systematically studied in colloidal solutions at room temperature. The UC emission bands at 520 and 550 nm have been shifted to the longer-wavelength (ca. 6...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 28(2012), 50 vom: 18. Dez., Seite 17419-25
1. Verfasser: Bavykin, Dmitry V (VerfasserIn)
Weitere Verfasser: Stuchinskaya, Tanya L, Danos, Lefteris, Russell, David A
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2012
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Metals, Rare Earth Titanium D1JT611TNE
Beschreibung
Zusammenfassung:The radiative energy transfer from rare earth fluoride upconverting (UC) Na(x)Li(y)YF(4):Yb(3+),Er(3+) nanoparticles to rhodamine dyes has been systematically studied in colloidal solutions at room temperature. The UC emission bands at 520 and 550 nm have been shifted to the longer-wavelength (ca. 600 nm) region suitable for biomedical applications. To decrease the optical length between the upconverting emitter and the fluorophore, the UC nanoparticles were decorated with titanate nanotubes coated with a dense layer of dye molecules providing possible resonance-energy transfer between them. The fabricated nanostructured composite shows efficient harvesting of UC emission within the proximity of the nanoparticles, allowing the local generation of light suitable for photodynamic therapy applications
Beschreibung:Date Completed 23.05.2013
Date Revised 21.11.2013
published: Print-Electronic
Citation Status MEDLINE
ISSN:1520-5827
DOI:10.1021/la304043d