Chiral nematic stained glass : controlling the optical properties of nanocrystalline cellulose-templated materials

Chiral nematic mesoporous materials decorated with metal nanoparticles have been prepared using the templated self-assembly of nanocrystalline cellulose (NCC). By adding small quantities of ionic compounds to aqueous dispersions of NCC and tetramethoxysilane (TMOS), the helical pitch of the chiral n...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 28(2012), 50 vom: 18. Dez., Seite 17256-62
1. Verfasser: Kelly, Joel A (VerfasserIn)
Weitere Verfasser: Shopsowitz, Kevin E, Ahn, Jun Myun, Hamad, Wadood Y, MacLachlan, Mark J
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2012
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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520 |a Chiral nematic mesoporous materials decorated with metal nanoparticles have been prepared using the templated self-assembly of nanocrystalline cellulose (NCC). By adding small quantities of ionic compounds to aqueous dispersions of NCC and tetramethoxysilane (TMOS), the helical pitch of the chiral nematic structure could be manipulated in a manner complementary to the ratio of NCC/TMOS previously demonstrated by our group. We have studied the transformation of these ion-loaded composites into high surface area mesoporous silica and carbon films decorated with metal nanoparticles through calcination and carbonization, respectively. This general and straightforward approach to prepare chiral nematic metal nanoparticle assemblies may be useful in a variety of applications, particularly for their chiral optical properties 
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700 1 |a Ahn, Jun Myun  |e verfasserin  |4 aut 
700 1 |a Hamad, Wadood Y  |e verfasserin  |4 aut 
700 1 |a MacLachlan, Mark J  |e verfasserin  |4 aut 
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