Effect of immobilized amines on the sorption properties of solid materials : impregnation versus grafting
The underlying mechanism of the adsorption process in functionalized materials is not yet fully understood. This incomplete understanding limits the possibility of designing optimal adsorbent materials for different applications. Hence, the availability of complementary methods to advance this field...
| Veröffentlicht in: | Langmuir : the ACS journal of surfaces and colloids. - 1992. - 29(2013), 1 vom: 08. Jan., Seite 199-206 |
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| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2013
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| Zugriff auf das übergeordnete Werk: | Langmuir : the ACS journal of surfaces and colloids |
| Schlagworte: | Journal Article |
| Zusammenfassung: | The underlying mechanism of the adsorption process in functionalized materials is not yet fully understood. This incomplete understanding limits the possibility of designing optimal adsorbent materials for different applications. Hence, the availability of complementary methods to advance this field is of great interest. We present here results concerning the adsorption of CO(2) in amine-functionalized silica materials by Monte Carlo simulations, providing new insights into the capture process. Two different mechanisms of functionalization are compared: impregnation (a physical mixture of the amine and the support) and grafting (a chemical bond is formed between the amine and the support). We evaluate in this work a model of MCM-41 for N(2) and CO(2) adsorption with varying degrees of density of the functionalized chains. The results indicate that the mobility of the impregnated chains allows the creation of a network of microcavities, which enhance the low-pressure adsorption capabilities of these materials. Molecular simulations allow us to study in detail the conformational changes in the functionalized chains during the adsorption process. Materials functionalized densely by grafting undergo a change in the preferential orientation of the chains, which allows the adsorption of additional molecules close to the surface of the support. The adsorption of gas molecules close to the pore surface is usually the most energetically favorable configuration; however, for densely grafted materials the adsorption close to the surface occurs only at pressures large enough to provide energy to displace the functionalized chains |
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| Beschreibung: | Date Completed 14.06.2013 Date Revised 08.01.2013 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1520-5827 |
| DOI: | 10.1021/la3038507 |