UV-initiated hydrosilylation on hydrogen-terminated silicon (111) : rate coefficient increase of two orders of magnitude in the presence of aromatic electron acceptors

UV-initiated (254 nm) hydrosilylation of hexadecene on Si(111)-H has been studied in the presence of various aliphatic and aromatic molecules (additives). Many of these additives cause an enhancement in the pseudo-first-order rate coefficient (k(obs)) of hydrosilylation, some up to 200× faster than...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 28(2012), 47 vom: 27. Nov., Seite 16285-93
1. Verfasser: Huck, Lawrence A (VerfasserIn)
Weitere Verfasser: Buriak, Jillian M
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2012
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article