Directed coassembly of oriented PbS nanoparticles and monocrystalline sheets of alkylamine surfactant

We demonstrate control over the orientation of PbS nanoparticles by way of directed assembly, which in turn affects the crystal structure of alkylamine surfactants such as octadecylamine (ODA, C(18)H(37)NH(2)) and hexadecylamine (HDA, C(16)H(33)NH(2)). This directed assembly method results in the ar...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 28(2012), 43 vom: 30. Okt., Seite 15119-23
1. Verfasser: Rabkin, Alexander (VerfasserIn)
Weitere Verfasser: Belman, Nataly, Israelachvili, Jacob, Golan, Yuval
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2012
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
Beschreibung
Zusammenfassung:We demonstrate control over the orientation of PbS nanoparticles by way of directed assembly, which in turn affects the crystal structure of alkylamine surfactants such as octadecylamine (ODA, C(18)H(37)NH(2)) and hexadecylamine (HDA, C(16)H(33)NH(2)). This directed assembly method results in the arrangement of PbS nanoparticles with a well-defined epitaxial orientation on lamellar alkylamine sheets, which undertake a new crystal structure to accommodate these relations. Understanding these surfactant-nanoparticle inter-relations is very instrumental in understanding surfactant-assisted nanoparticle synthesis and assembly
Beschreibung:Date Completed 26.03.2013
Date Revised 30.10.2012
published: Print-Electronic
Citation Status PubMed-not-MEDLINE
ISSN:1520-5827
DOI:10.1021/la303747x