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231224s2013 xx |||||o 00| ||eng c |
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|a 10.1016/j.wasman.2012.08.005
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|a pubmed24n0736.xml
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|a (DE-627)NLM22104907X
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|a (NLM)22980910
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|a (PII)S0956-053X(12)00371-6
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|a DE-627
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|c DE-627
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|a eng
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|a Singh, Shrawan K
|e verfasserin
|4 aut
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|a Statistical analysis of optimum Fenton oxidation conditions for landfill leachate treatment
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|c 2013
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|a Text
|b txt
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|2 rdacarrier
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|a Date Completed 21.05.2013
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|a Date Revised 21.11.2013
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|a published: Print-Electronic
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|a Citation Status MEDLINE
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|a Copyright © 2012 Elsevier Ltd. All rights reserved.
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|a Optimal operating conditions observed by peer reviewed publications for Fenton oxidation of raw and biological and coagulation treated leachates were reviewed and statistically analyzed. For the first-stage Fenton oxidation, the optimal pH range of 2.5-4.5 was observed for raw and coagulation treated leachates with a median pH of 3.0, whereas, for biologically treated leachate the optimum pH range was 2.5-6.0 with a median pH of 4.2. Theoretically, the optimal ratio of H(2)O(2)/Fe(2+) should be the ratio of rate constants of the reactions between OH() radical with Fe(2+) and H(2)O(2), which is approximately 11; however, for leachate treatment, a median optimum relative dose of 1.8 (w/w) (3.0M/M) was observed. Biologically treated leachate showed relatively lower optimum ratio of H(2)O(2)/Fe(2+) doses (median: 0.9 w/w) as compared to raw (median: 2.4 w/w) and coagulation treated (median: 2.8 w/w) leachate. Median absolute doses of H(2)O(2) and Fe(2+) were 1.2mg H(2)O(2)/mg of initial COD (COD(0)) and 0.9 mg Fe(2+)/mg COD(0), respectively and raw leachate required higher reagent doses compared to pretreated leachates. A universal Fenton oxidation relationship between COD removal efficiency (η) and COD loading factor (L(COD)) for landfill leachate treatment was developed. As L(COD) increases from 0.03 to 72.0, η varies linearly as η=0.733 L(COD)-0.182. This robust linear relationship between L(COD) and η holds for Fenton oxidation of raw as well as biological and coagulation treated leachates. The relationship was validated using Leave-one-out cross validation technique and errors in predicting η using L(COD) were evaluated by applying Monte Carlo Simulation. As a result, the relationship can be used as a universal equation to predict Fenton treatment efficiency for a given COD(0) loading in the range of 0.03-72.0 for landfill leachate treatment
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|a Journal Article
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|a Research Support, Non-U.S. Gov't
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|a Review
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|a Fenton's reagent
|2 NLM
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|a Organic Chemicals
|2 NLM
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|a Water Pollutants, Chemical
|2 NLM
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|a Hydrogen Peroxide
|2 NLM
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|a BBX060AN9V
|2 NLM
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|a Iron
|2 NLM
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|a E1UOL152H7
|2 NLM
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|a Tang, Walter Z
|e verfasserin
|4 aut
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|i Enthalten in
|t Waste management (New York, N.Y.)
|d 1999
|g 33(2013), 1 vom: 14. Jan., Seite 81-8
|w (DE-627)NLM098197061
|x 1879-2456
|7 nnns
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|g volume:33
|g year:2013
|g number:1
|g day:14
|g month:01
|g pages:81-8
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|u http://dx.doi.org/10.1016/j.wasman.2012.08.005
|3 Volltext
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