Revised structures of avenacosides A and B and a new sulfated saponin from Avena sativa L

Copyright © 2012 John Wiley & Sons, Ltd.

Détails bibliographiques
Publié dans:Magnetic resonance in chemistry : MRC. - 1985. - 50(2012), 11 vom: 01. Nov., Seite 755-8
Auteur principal: Pecio, Łukasz (Auteur)
Autres auteurs: Jędrejek, Dariusz, Masullo, Milena, Piacente, Sonia, Oleszek, Wiesław, Stochmal, Anna
Format: Article en ligne
Langue:English
Publié: 2012
Accès à la collection:Magnetic resonance in chemistry : MRC
Sujets:Journal Article Saponins avenacoside A avenacoside B
Description
Résumé:Copyright © 2012 John Wiley & Sons, Ltd.
The revised structures of avenacosides A and B and a new sulfated steroidal saponin isolated from grains of Avena sativa L. were elucidated. Their structures and complete NMR assignments are based on 1D and 2D NMR studies and identified as nuatigenin 3-O-{α-L-rhamnopyranosyl-(1→2)-[β-D-glucopyranosyl-(1→4)]-β-D-glucopyranoside}-26-O-β-D-glucopyranoside (1), nuatigenin 3-O-{α-L-rhamnopyranosyl-(1→2)-[β-D-glucopyranosyl-(1→3)-β-D-glucopyranosyl-(1→4)]-β-D-glucopyranoside}-26-O-β-D-glucopyranoside (2), and nuatigenin 3-O-{α-L-rhamnopyranosyl-(1→2)-[β-D-6-O-sulfoglucopyranosyl-(1→4)]-β-D-glucopyranoside}-26-O-β-D-glucopyranoside (3)
Description:Date Completed 05.08.2013
Date Revised 18.03.2022
published: Print-Electronic
Citation Status MEDLINE
ISSN:1097-458X
DOI:10.1002/mrc.3869