Revised structures of avenacosides A and B and a new sulfated saponin from Avena sativa L
Copyright © 2012 John Wiley & Sons, Ltd.
Publié dans: | Magnetic resonance in chemistry : MRC. - 1985. - 50(2012), 11 vom: 01. Nov., Seite 755-8 |
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Auteur principal: | |
Autres auteurs: | , , , , |
Format: | Article en ligne |
Langue: | English |
Publié: |
2012
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Accès à la collection: | Magnetic resonance in chemistry : MRC |
Sujets: | Journal Article Saponins avenacoside A avenacoside B |
Résumé: | Copyright © 2012 John Wiley & Sons, Ltd. The revised structures of avenacosides A and B and a new sulfated steroidal saponin isolated from grains of Avena sativa L. were elucidated. Their structures and complete NMR assignments are based on 1D and 2D NMR studies and identified as nuatigenin 3-O-{α-L-rhamnopyranosyl-(1→2)-[β-D-glucopyranosyl-(1→4)]-β-D-glucopyranoside}-26-O-β-D-glucopyranoside (1), nuatigenin 3-O-{α-L-rhamnopyranosyl-(1→2)-[β-D-glucopyranosyl-(1→3)-β-D-glucopyranosyl-(1→4)]-β-D-glucopyranoside}-26-O-β-D-glucopyranoside (2), and nuatigenin 3-O-{α-L-rhamnopyranosyl-(1→2)-[β-D-6-O-sulfoglucopyranosyl-(1→4)]-β-D-glucopyranoside}-26-O-β-D-glucopyranoside (3) |
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Description: | Date Completed 05.08.2013 Date Revised 18.03.2022 published: Print-Electronic Citation Status MEDLINE |
ISSN: | 1097-458X |
DOI: | 10.1002/mrc.3869 |