A simple and accurate analytical method for determination of three commercial dyes in different water systems using partial least squares regression
A simple analytical procedure is proposed for simultaneous determination of three common dyes (Basic Blue 9, Brilliant Blue E-4BA, and Reactive Blue 2) in natural waters without prior separation of the solutes. A popular chemometric method, partial least squares regression PLS-1, was effectively app...
| Veröffentlicht in: | Water science and technology : a journal of the International Association on Water Pollution Research. - 1986. - 66(2012), 8 vom: 01., Seite 1647-55 |
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| Weitere Verfasser: | , , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2012
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| Zugriff auf das übergeordnete Werk: | Water science and technology : a journal of the International Association on Water Pollution Research |
| Schlagworte: | Journal Article Research Support, Non-U.S. Gov't Coloring Agents Thiazines Methylene Blue T42P99266K |
| Zusammenfassung: | A simple analytical procedure is proposed for simultaneous determination of three common dyes (Basic Blue 9, Brilliant Blue E-4BA, and Reactive Blue 2) in natural waters without prior separation of the solutes. A popular chemometric method, partial least squares regression PLS-1, was effectively applied for spectral resolution of a highly overlapping system. At the best modeling conditions, mean recoveries and relative standard deviations (RSD) for dyes quantification by PLS-1 were found to be 102.1 (4.4), 95.7 (8.4), and 98.9 (6.2) for Basic Blue, Brilliant Blue, and Reactive Blue, respectively. The estimated limits of detection (LOD) were estimated using net-analyte signal concept and were 0.11, 0.52, 0.49 mg L(-1) for Basic Blue, Brilliant Blue, and Reactive Blue, respectively. The quantitative determination of dyes spiked in real water samples was carried out successfully by PLS-1 with satisfactory recoveries for dyes (90-106%) |
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| Beschreibung: | Date Completed 27.11.2012 Date Revised 01.12.2018 published: Print Citation Status MEDLINE |
| ISSN: | 0273-1223 |
| DOI: | 10.2166/wst.2012.364 |