Metallic film formation using direct micropatterning with photoreactive metal complexes

Palladium, cobalt, and nickel in complex with photoacid-generating ligands, 4-(2-nitrobenzyloxycarbonyl)catechol and 4-(6-nitroveratryloxycarbonyl)catechol, were prepared in solution. Films formed from the metal complex solutions perform as positive-tone, directly photopatternable palladium, cobalt,...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1999. - 28(2012), 37 vom: 18. Sept., Seite 13542-8
1. Verfasser: Cordonier, Christopher E J (VerfasserIn)
Weitere Verfasser: Nakamura, Akimasa, Shimada, Kazuhiko, Fujishima, Akira
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2012
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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520 |a Palladium, cobalt, and nickel in complex with photoacid-generating ligands, 4-(2-nitrobenzyloxycarbonyl)catechol and 4-(6-nitroveratryloxycarbonyl)catechol, were prepared in solution. Films formed from the metal complex solutions perform as positive-tone, directly photopatternable palladium, cobalt, nickel oxide, or composite film precursors. After exposure, acid-bearing selectively soluble complexes could be removed to give patterned films upon developing in aqueous base, which were transformable to the corresponding pattern-preserving metal/metal oxide film. The photodynamics of photoinduced solubility and direct micropatterning of palladium, cobalt, nickel, and palladium/nickel oxide composite films were investigated. Employing palladium as the initiator for autocatalytic chemical plating, selective direct copper plating on palladium film on polyethylene naphthalate and palladium/nickel oxide composite film on glass was accomplished 
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700 1 |a Nakamura, Akimasa  |e verfasserin  |4 aut 
700 1 |a Shimada, Kazuhiko  |e verfasserin  |4 aut 
700 1 |a Fujishima, Akira  |e verfasserin  |4 aut 
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