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231224s2012 xx |||||o 00| ||eng c |
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|a 10.1021/la300942f
|2 doi
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|a eng
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|a Sharma, Suraj Chandra
|e verfasserin
|4 aut
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| 245 |
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|a Phase behavior, self-assembly, and emulsification of Tween 80/water mixtures with limonene and perfluoromethyldecalin
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|c 2012
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|a Date Completed 18.12.2012
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|a Date Revised 14.08.2012
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a The phase behavior, microstructure, and emulsification of polyoxyethylene (20) sorbitan monooleate (Tween 80), water, and d-limonene (LM) or perfluoromethyldecalin (PFMD) has been studied by small-angle X-ray scattering and polarizing optical microscopy. In the Tween 80/water binary system, a micellar solution (L(1)), a hexagonal (H(1)) phase, and a water-swellable isotropic surfactant liquid (L(2)) phase are successively formed at 25 °C. LM can be solubilized into all of the phases formed by Tween 80/water mixtures, whereas no solubilization of PFMD occurs. The L(2) phase was found by small-angle neutron scattering to be bicontinuous with low interfacial curvature. Added water swells and amplifies the pre-existing amphiphilic structure. The stability of oil-in-H(1) complex emulsions is found to be sensitive to changes in structure that accompany solubilization
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|a Journal Article
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|a Warr, Gregory G
|e verfasserin
|4 aut
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 28(2012), 32 vom: 14. Aug., Seite 11707-13
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|g year:2012
|g number:32
|g day:14
|g month:08
|g pages:11707-13
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