Optimization of an adsorption process for tetrafluoroborate removal by zirconium (IV)-loaded orange waste gel from aqueous solution

This investigation provides new insights into the effective removal of tetrafluoroborate (BF4-) by means of bio-sorption on waste generated in the orange juice industry. It was undertaken to evaluate the feasibility of zirconium (IV)-loaded saponified orange waste gel for BF4- removal from an aqueou...

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Veröffentlicht in:Environmental technology. - 1998. - 33(2012), 7-9 vom: 08. Apr., Seite 845-50
1. Verfasser: Pangeni, Bimala (VerfasserIn)
Weitere Verfasser: Paudyal, Hari, Inoue, Katsutoshi, Kawakita, Hidetaka, Ohto, Keisuke, Harada, Hiroyuki, Biswas, Biplob Kumar, Alam, Shafiq
Format: Aufsatz
Sprache:English
Veröffentlicht: 2012
Zugriff auf das übergeordnete Werk:Environmental technology
Schlagworte:Evaluation Study Journal Article Research Support, Non-U.S. Gov't Anions Borates Boric Acids Water Pollutants, Chemical Zirconium C6V6S92N3C fluoroboric acid H429WZ9FBQ
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520 |a This investigation provides new insights into the effective removal of tetrafluoroborate (BF4-) by means of bio-sorption on waste generated in the orange juice industry. It was undertaken to evaluate the feasibility of zirconium (IV)-loaded saponified orange waste gel for BF4- removal from an aqueous solution. Batch adsorption experiments were carried out to study the influence of various factors such as pH, presence of competing anions, contact time, initial BF4- concentration and temperature on the adsorption of BF4-. The optimum BF4- removal was observed in the equilibrium pH region 2-3. The presence of coexisting anions showed no adverse effect on BF4- removal except SO4(2-). The equilibrium data at different temperatures were reasonably interpreted by the Langmuir adsorption isotherm and the maximum adsorption capacities were evaluated as 2.65, 3.28, 3.87 and 4.77 mmol g(-1) at 293, 298, 303 and 313 K, respectively. Thermodynamic parameters such as deltaGo, deltaHo and deltaSo indicated that the nature of BF4- adsorption is spontaneous and endothermic. The results obtained from this study demonstrate the potential usability of orange waste after juicing as a good BF4- selective adsorbent 
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650 4 |a Journal Article 
650 4 |a Research Support, Non-U.S. Gov't 
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650 7 |a Zirconium  |2 NLM 
650 7 |a C6V6S92N3C  |2 NLM 
650 7 |a fluoroboric acid  |2 NLM 
650 7 |a H429WZ9FBQ  |2 NLM 
700 1 |a Paudyal, Hari  |e verfasserin  |4 aut 
700 1 |a Inoue, Katsutoshi  |e verfasserin  |4 aut 
700 1 |a Kawakita, Hidetaka  |e verfasserin  |4 aut 
700 1 |a Ohto, Keisuke  |e verfasserin  |4 aut 
700 1 |a Harada, Hiroyuki  |e verfasserin  |4 aut 
700 1 |a Biswas, Biplob Kumar  |e verfasserin  |4 aut 
700 1 |a Alam, Shafiq  |e verfasserin  |4 aut 
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