|
|
|
|
| LEADER |
01000naa a22002652 4500 |
| 001 |
NLM218520840 |
| 003 |
DE-627 |
| 005 |
20231224040642.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
231224s2012 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1021/la302050m
|2 doi
|
| 028 |
5 |
2 |
|a pubmed24n0728.xml
|
| 035 |
|
|
|a (DE-627)NLM218520840
|
| 035 |
|
|
|a (NLM)22686576
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Stadie, Nicholas P
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Zeolite-templated carbon materials for high-pressure hydrogen storage
|
| 264 |
|
1 |
|c 2012
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Completed 13.11.2012
|
| 500 |
|
|
|a Date Revised 18.11.2021
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a Zeolite-templated carbon (ZTC) materials were synthesized, characterized, and evaluated as potential hydrogen storage materials between 77 and 298 K up to 30 MPa. Successful synthesis of high template fidelity ZTCs was confirmed by X-ray diffraction and nitrogen adsorption at 77 K; BET surface areas up to ~3600 m(2) g(-1) were achieved. Equilibrium hydrogen adsorption capacity in ZTCs is higher than all other materials studied, including superactivated carbon MSC-30. The ZTCs showed a maximum in Gibbs surface excess uptake of 28.6 mmol g(-1) (5.5 wt %) at 77 K, with hydrogen uptake capacity at 300 K linearly proportional to BET surface area: 2.3 mmol g(-1) (0.46 wt %) uptake per 1000 m(2) g(-1) at 30 MPa. This is the same trend as for other carbonaceous materials, implying that the nature of high-pressure adsorption in ZTCs is not unique despite their narrow microporosity and significantly lower skeletal densities. Isoexcess enthalpies of adsorption are calculated between 77 and 298 K and found to be 6.5-6.6 kJ mol(-1) in the Henry's law limit
|
| 650 |
|
4 |
|a Journal Article
|
| 700 |
1 |
|
|a Vajo, John J
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Cumberland, Robert W
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Wilson, Andrew A
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Ahn, Channing C
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Fultz, Brent
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 28(2012), 26 vom: 03. Juli, Seite 10057-63
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
|
| 773 |
1 |
8 |
|g volume:28
|g year:2012
|g number:26
|g day:03
|g month:07
|g pages:10057-63
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1021/la302050m
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_22
|
| 912 |
|
|
|a GBV_ILN_350
|
| 912 |
|
|
|a GBV_ILN_721
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 28
|j 2012
|e 26
|b 03
|c 07
|h 10057-63
|