Interface-directed self-assembly of gold nanoparticles and fabrication of hybrid hollow capsules by interfacial cross-linking polymerization

Amphiphilic gold nanoparticles (AuNPs) were produced at liquid-liquid interface via ligand exchange between hydrophilic AuNPs and disulfide-containing polymer chains. By using oil droplets as templates, hybrid hollow capsules with AuNPs on the surfaces were obtained after interfacial cross-linking p...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 28(2012), 25 vom: 26. Juni, Seite 9365-71
1. Verfasser: Tian, Jia (VerfasserIn)
Weitere Verfasser: Yuan, Liang, Zhang, Mingming, Zheng, Fan, Xiong, Qingqing, Zhao, Hanying
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2012
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Acrylic Resins Capsules Solvents Gold 7440-57-5 polyacrylamide 9003-05-8
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520 |a Amphiphilic gold nanoparticles (AuNPs) were produced at liquid-liquid interface via ligand exchange between hydrophilic AuNPs and disulfide-containing polymer chains. By using oil droplets as templates, hybrid hollow capsules with AuNPs on the surfaces were obtained after interfacial cross-linking polymerization. The volume ratio of toluene to water exerts an important effect on the size of capsules. The average size of the capsules increases with the volume ratio. Transmission electron microscopy (TEM), scanning electron microscopy (SEM), and atomic force microscopy (AFM) were used to characterize the hollow structures. In this research, not only one-component but also multicomponent hollow capsules were prepared by copolymerization of acrylamide and hybrid AuNPs at liquid-liquid interface. Because of the improvement in hydrophilicity of the hollow capsules, the average size of multicomponent capsules is bigger than one-component ones in aqueous solution 
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650 4 |a Research Support, Non-U.S. Gov't 
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650 7 |a Gold  |2 NLM 
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650 7 |a polyacrylamide  |2 NLM 
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700 1 |a Yuan, Liang  |e verfasserin  |4 aut 
700 1 |a Zhang, Mingming  |e verfasserin  |4 aut 
700 1 |a Zheng, Fan  |e verfasserin  |4 aut 
700 1 |a Xiong, Qingqing  |e verfasserin  |4 aut 
700 1 |a Zhao, Hanying  |e verfasserin  |4 aut 
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