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231224s2012 xx |||||o 00| ||eng c |
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|a 10.1021/la3011597
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|a eng
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|a Qiao, Junqiang
|e verfasserin
|4 aut
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|a Addition of halloysite nanotubes prevents cracking in drying latex films
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|c 2012
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|a Text
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|a ƒaComputermedien
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|a Date Completed 04.10.2012
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|a Date Revised 12.06.2012
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a Investigating the process of film drying from aqueous dispersions containing a polymer latex as well as halloysite nanotubes (HNTs), we found that composite films could be formed without cracking under conditions where films of the pure polymer would always crack. Scanning electron micrographs showed that the HNTs were well dispersed and, further, that the distribution of fiber orientations was close to isotropic. The pendulum hardness of films formed from acrylate dispersions strongly increased upon addition of the inorganic phase. The pencil hardness, on the other hand, was poor, which presumably goes back to insufficient coupling between the organic and the inorganic phase. All films were white in appearance. For fiber concentrations higher than 10 vol %, the final films were porous
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|a Journal Article
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|a Adams, Jörg
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|a Johannsmann, Diethelm
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|t Langmuir : the ACS journal of surfaces and colloids
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