Effects of oxidant concentration and temperature on decolorization of azo dye : comparisons of UV/Fenton and UV/Fenton-like systems

This study applies photo-Fenton and photo-Fenton-like systems to decolorize C.I. Reactive Red 2 (RR2). The oxidants were H(2)O(2) and Na(2)S(2)O(8); Fe(2+), Fe(3+), and Co(2+) were used to activate these two oxidants. The effects of oxidant concentration (0.3-2 mmol/L) and temperature (25-55 °C) on...

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Veröffentlicht in:Water science and technology : a journal of the International Association on Water Pollution Research. - 1986. - 65(2012), 11 vom: 14., Seite 1970-4
1. Verfasser: Kuo, C Y (VerfasserIn)
Weitere Verfasser: Pai, C Y, Wu, C H, Jian, M Y
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2012
Zugriff auf das übergeordnete Werk:Water science and technology : a journal of the International Association on Water Pollution Research
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Fenton's reagent Naphthalenesulfonates Oxidants Triazines Water Pollutants, Chemical reactive red 2 Hydrogen Peroxide BBX060AN9V mehr... Iron E1UOL152H7
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520 |a This study applies photo-Fenton and photo-Fenton-like systems to decolorize C.I. Reactive Red 2 (RR2). The oxidants were H(2)O(2) and Na(2)S(2)O(8); Fe(2+), Fe(3+), and Co(2+) were used to activate these two oxidants. The effects of oxidant concentration (0.3-2 mmol/L) and temperature (25-55 °C) on decolorization efficiency of the photo-Fenton and photo-Fenton-like systems were determined. The decolorization rate constants (k) of RR2 in the tested systems are consistent with pseudo-first-order kinetics. The rate constant increased as oxidant concentration and temperature increased. Activation energies of RR2 decolorization in the UV/H(2)O(2)/Fe(2+), UV/H(2)O(2)/Fe(3+), UV/Na(2)S(2)O(8)/Fe(2+) and UV/Na(2)S(2)O(8)/Fe(3+) systems were 32.20, 39.54, 35.54, and 51.75 kJ/mol, respectively 
650 4 |a Journal Article 
650 4 |a Research Support, Non-U.S. Gov't 
650 7 |a Fenton's reagent  |2 NLM 
650 7 |a Naphthalenesulfonates  |2 NLM 
650 7 |a Oxidants  |2 NLM 
650 7 |a Triazines  |2 NLM 
650 7 |a Water Pollutants, Chemical  |2 NLM 
650 7 |a reactive red 2  |2 NLM 
650 7 |a Hydrogen Peroxide  |2 NLM 
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650 7 |a Iron  |2 NLM 
650 7 |a E1UOL152H7  |2 NLM 
700 1 |a Pai, C Y  |e verfasserin  |4 aut 
700 1 |a Wu, C H  |e verfasserin  |4 aut 
700 1 |a Jian, M Y  |e verfasserin  |4 aut 
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773 1 8 |g volume:65  |g year:2012  |g number:11  |g day:14  |g pages:1970-4 
856 4 0 |u http://dx.doi.org/10.2166/wst.2012.095  |3 Volltext 
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