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231224s2012 xx |||||o 00| ||eng c |
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|a 10.1021/la301023k
|2 doi
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|a eng
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| 100 |
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|a Erni, Philipp
|e verfasserin
|4 aut
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| 245 |
1 |
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|a Nonlinear viscoelasticity and shear localization at complex fluid interfaces
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|c 2012
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|a Text
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|a Date Completed 28.09.2012
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|a Date Revised 19.07.2012
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|a published: Print-Electronic
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|a Citation Status MEDLINE
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|a Foams and emulsions are often exposed to strong external fields, resulting in large interface deformations far beyond the linear viscoelastic regime. Here, we investigate the nonlinear and transient interfacial rheology of adsorption layers in large-amplitude oscillatory shear flow. As a prototypical material forming soft-solid-type interfacial adsorption layers, we use Acacia gum (i.e., gum arabic), a protein/polysaccharide hybrid. We quantify its nonlinear flow properties at the oil/water interface using a biconical disk interfacial rheometer and analyze the nonlinear stress response under forced strain oscillations. From the resulting Lissajous curves, we access quantitative measures recently introduced for nonlinear viscoelasticity, including the intracycle moduli for both the maximum and zero strains and the degree of plastic energy dissipation upon interfacial yielding. We demonstrate using in situ flow visualization that the onset of nonlinear viscoelasticity coincides with shear localization at the interface. Finally, we address the nonperiodic character of this flow transition using an experimental procedure based on opposing stress pulses, allowing us to extract additional interfacial properties such as the critical interfacial stress upon yielding and the permanent deformation
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|a Journal Article
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1 |
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|a Parker, Alan
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 28(2012), 20 vom: 22. Mai, Seite 7757-67
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|u http://dx.doi.org/10.1021/la301023k
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