Oxidation of bisphenol A by UV/S2O8(2-) : comparison with UV/H2O2

The UV/S2O8(2-) process was applied to decompose bisphenol A (BPA), which is a representative endocrine-disrupting chemical (EDC), and was comared with the UV/H2O2 process. The BPA degradation efficiency by UV/S2O8(2-) was increased by increasing S2O8(2-) concentration or decreasing BPA concentratio...

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Veröffentlicht in:Environmental technology. - 1993. - 33(2012), 1-3 vom: 01. Jan., Seite 123-8
1. Verfasser: Yoon, Sung-Hwan (VerfasserIn)
Weitere Verfasser: Jeong, Seongpil, Lee, Seockheon
Format: Aufsatz
Sprache:English
Veröffentlicht: 2012
Zugriff auf das übergeordnete Werk:Environmental technology
Schlagworte:Comparative Study Journal Article Benzhydryl Compounds Endocrine Disruptors Humic Substances Phenols Sulfates sulfate radical Ethanol 3K9958V90M mehr... Hydrogen Peroxide BBX060AN9V tert-Butyl Alcohol MD83SFE959 bisphenol A MLT3645I99
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520 |a The UV/S2O8(2-) process was applied to decompose bisphenol A (BPA), which is a representative endocrine-disrupting chemical (EDC), and was comared with the UV/H2O2 process. The BPA degradation efficiency by UV/S2O8(2-) was increased by increasing S2O8(2-) concentration or decreasing BPA concentration. The presence of humic acid caused an inhibitory effect. The BPA oxidation rate by UV/S2O8(2-) was increased in the following order: neutral pH (pH(i) = 7) < acidic pH (pH(i) = 4) < basic pH (pH(i) = 10). The main oxidizing species in the UV/S2O8(2-) system was sulphate radical (SO4(-*)), whereas the main oxidizing species in the UV/H2O2 system was OH radical (OH*). Compared with UV/H2O2, the UV/S2O8(2-) process showed higher performance for not only BPA degradation but also its mineralization, which means that SO4(-*) is a more effective oxidant for BPA than the OH*. The results shown in this study imply that the SO4(-*) -based UV/S2O8(2-) process can be an excellent alternative process for the widely used UV/H2O2 process, with higher remediation performance 
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