Peculiarities of intramolecular exchange and valence tautomerism in metal semiquinolates determined by high-resolution NMR spectroscopy

Peculiarities of intramolecular exchange and valence tautomerism in metal semiquinolates determined by high-resolution NMR spectroscopy

Copyright © 2012 John Wiley & Sons, Ltd.

Bibliographische Detailangaben
Veröffentlicht in:Magnetic resonance in chemistry : MRC. - 1985. - 50(2012), 5 vom: 06. Mai, Seite 350-6
1. Verfasser: Voronov, Vladimir K (VerfasserIn)
Weitere Verfasser: Ushakov, Igor A, Shmelev, Vadim V, Sagdeev, Dmitry R
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2012
Zugriff auf das übergeordnete Werk:Magnetic resonance in chemistry : MRC
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Coordination Complexes Toluene 3FPU23BG52 Cobalt 3G0H8C9362 Quinolinic Acid F6F0HK1URN
Beschreibung
Zusammenfassung:Copyright © 2012 John Wiley & Sons, Ltd.
The (1)H NMR spectra of semiquinalate cobalt complex have been analyzed in a wide range of temperatures. It has been established that the intramolecular exchange requires the obligatory presence of a paramagnetic structure containing non-compensated electron spin localized on the carbon atom of the ligand aromatic ring, the cobalt atom being trivalent. The presence of such a structure leads to the appearance of satellite signals in the NMR spectra because of the superfine interactions
Beschreibung:Date Completed 28.08.2012
Date Revised 21.11.2013
published: Print-Electronic
Citation Status MEDLINE
ISSN:1097-458X
DOI:10.1002/mrc.3799