Solution behavior of normal and reverse triblock copolymers (pluronic L44 and 10R5) individually and in binary mixture

Solution properties of pluronics L44 or L [(PEO)(10)(PPO)(23)(PEO)(10)] and 10R5 or R [(PPO)(8)(PEO)(22)(PPO)(8)] were studied individually as well in their binary mixtures in aqueous medium. The critical micelle concentration (CMC), critical micelle temperature, and cloud point (CP) were determined...

Ausführliche Beschreibung

Bibliographische Detailangaben
Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 28(2012), 18 vom: 08. Mai, Seite 7134-46
1. Verfasser: Naskar, Bappaditya (VerfasserIn)
Weitere Verfasser: Ghosh, Soumen, Moulik, Satya P
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2012
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Anti-Bacterial Agents Complex Mixtures Micelles Solutions Poloxamer 106392-12-5
LEADER 01000naa a22002652 4500
001 NLM217043658
003 DE-627
005 20231224033144.0
007 cr uuu---uuuuu
008 231224s2012 xx |||||o 00| ||eng c
024 7 |a 10.1021/la3000729  |2 doi 
028 5 2 |a pubmed24n0723.xml 
035 |a (DE-627)NLM217043658 
035 |a (NLM)22506970 
040 |a DE-627  |b ger  |c DE-627  |e rakwb 
041 |a eng 
100 1 |a Naskar, Bappaditya  |e verfasserin  |4 aut 
245 1 0 |a Solution behavior of normal and reverse triblock copolymers (pluronic L44 and 10R5) individually and in binary mixture 
264 1 |c 2012 
336 |a Text  |b txt  |2 rdacontent 
337 |a ƒaComputermedien  |b c  |2 rdamedia 
338 |a ƒa Online-Ressource  |b cr  |2 rdacarrier 
500 |a Date Completed 29.08.2012 
500 |a Date Revised 08.05.2012 
500 |a published: Print-Electronic 
500 |a Citation Status MEDLINE 
520 |a Solution properties of pluronics L44 or L [(PEO)(10)(PPO)(23)(PEO)(10)] and 10R5 or R [(PPO)(8)(PEO)(22)(PPO)(8)] were studied individually as well in their binary mixtures in aqueous medium. The critical micelle concentration (CMC), critical micelle temperature, and cloud point (CP) were determined. Ideal and nonideal behaviors of their mixtures in the formation of CMC and CP were observed; the energetics of the studied processes were determined. Spectrophotometry, isothermal titration calorimetry and dynamic light scattering (DLS) methods were used for evaluations. Morphologies of the dispersed L, R, and their mixtures along with their polydispersities were determined from DLS measurements. Atomic force microscopy was also employed. The interfacial properties of L and R were investigated forming Langmuir monolayers in a surface balance. The surface pressures (π) generated by the compounds were moderate, the area per molecule was higher for R than L. R has shown antibacterial activity against both gram positive and gram negative bacteria whereas L was inactive in this respect 
650 4 |a Journal Article 
650 4 |a Research Support, Non-U.S. Gov't 
650 7 |a Anti-Bacterial Agents  |2 NLM 
650 7 |a Complex Mixtures  |2 NLM 
650 7 |a Micelles  |2 NLM 
650 7 |a Solutions  |2 NLM 
650 7 |a Poloxamer  |2 NLM 
650 7 |a 106392-12-5  |2 NLM 
700 1 |a Ghosh, Soumen  |e verfasserin  |4 aut 
700 1 |a Moulik, Satya P  |e verfasserin  |4 aut 
773 0 8 |i Enthalten in  |t Langmuir : the ACS journal of surfaces and colloids  |d 1992  |g 28(2012), 18 vom: 08. Mai, Seite 7134-46  |w (DE-627)NLM098181009  |x 1520-5827  |7 nnns 
773 1 8 |g volume:28  |g year:2012  |g number:18  |g day:08  |g month:05  |g pages:7134-46 
856 4 0 |u http://dx.doi.org/10.1021/la3000729  |3 Volltext 
912 |a GBV_USEFLAG_A 
912 |a SYSFLAG_A 
912 |a GBV_NLM 
912 |a GBV_ILN_22 
912 |a GBV_ILN_350 
912 |a GBV_ILN_721 
951 |a AR 
952 |d 28  |j 2012  |e 18  |b 08  |c 05  |h 7134-46