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231224s2012 xx |||||o 00| ||eng c |
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|a 10.1021/la300542y
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|a eng
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|a Szilagyi, Istvan
|e verfasserin
|4 aut
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|a Destabilization of colloidal suspensions by multivalent ions and polyelectrolytes
|b from screening to overcharging
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|c 2012
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|a Text
|b txt
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|a ƒaComputermedien
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|a ƒa Online-Ressource
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|a Date Completed 02.08.2012
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|a Date Revised 17.04.2012
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2012 American Chemical Society
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|a The destabilization of charged colloidal suspensions is studied in the presence of polyelectrolytes and the corresponding oligomers. Two different systems are investigated, namely, negatively charged particles in the presence of polyamines and positively charged ones in the presence of polycarboxylates. Multivalent oligomers of low valence destabilize the particles by screening according to the Schulze-Hardy rule. Polyelectrolytes induce destabilization by overcharging. Both regimes can be observed for oligomers of intermediate valence. The stability data of any valence can be rather well described by the theory of Derjaguin, Landau, Verwey, and Overbeek (DLVO), indicating that the interactions are mainly governed by van der Waals and electrostatic double-layer forces
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|a Journal Article
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|a Sadeghpour, Amin
|e verfasserin
|4 aut
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|a Borkovec, Michal
|e verfasserin
|4 aut
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1985
|g 28(2012), 15 vom: 17. Apr., Seite 6211-5
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|x 1520-5827
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|g volume:28
|g year:2012
|g number:15
|g day:17
|g month:04
|g pages:6211-5
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|u http://dx.doi.org/10.1021/la300542y
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