Preparation of N2/CO2 triggered reversibly coagulatable and redispersible latexes by emulsion polymerization of styrene with a reactive switchable surfactant

© 2012 American Chemical Society

Bibliographische Detailangaben
Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 28(2012), 14 vom: 10. Apr., Seite 5940-6
1. Verfasser: Zhang, Qi (VerfasserIn)
Weitere Verfasser: Yu, Guoqiang, Wang, Wen-Jun, Yuan, Haomiao, Li, Bo-Geng, Zhu, Shiping
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2012
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Acrylamides Electrolytes Emulsions Latex Surface-Active Agents Carbon Dioxide 142M471B3J Styrene mehr... 44LJ2U959V Nitrogen N762921K75
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245 1 0 |a Preparation of N2/CO2 triggered reversibly coagulatable and redispersible latexes by emulsion polymerization of styrene with a reactive switchable surfactant 
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500 |a Date Revised 21.11.2013 
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500 |a Citation Status MEDLINE 
520 |a © 2012 American Chemical Society 
520 |a This work reports the development of a reversibly coagulatable and redispersible polystyrene latex system that can be triggered by N(2)/CO(2). The coagulatability and redispersibility of the latexes were achieved by employing 0.9-5.6 wt % (N-amidino)dodecyl acrylamide (DAm), a reactive switchable surfactant, in an emulsion polymerization of styrene under CO(2) atmosphere. The resulted latex particles were readily coagulated by N(2) bubbling at 60 °C and redispersed by CO(2) bubbling and ultrasonication, which switched amidine moieties between neutral and ionic states. The coagulation/redispersion processes were repeatable. The prepared latexes showed good stabilities against electrolytes, especially with higher charges 
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650 4 |a Research Support, Non-U.S. Gov't 
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650 7 |a Emulsions  |2 NLM 
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700 1 |a Yu, Guoqiang  |e verfasserin  |4 aut 
700 1 |a Wang, Wen-Jun  |e verfasserin  |4 aut 
700 1 |a Yuan, Haomiao  |e verfasserin  |4 aut 
700 1 |a Li, Bo-Geng  |e verfasserin  |4 aut 
700 1 |a Zhu, Shiping  |e verfasserin  |4 aut 
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